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Flexural behaviour modelling of carbon/epoxy laminates using the puck-EWM approach 使用puck-EWM方法的碳/环氧层压板弯曲行为建模
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-31 DOI: 10.1080/14658011.2023.2252237
Hamza El idrissi, Y. Benbouras, M. Bellahkim, A. Seddouki, J. Echaabi
ABSTRACT To develop continuous fibre compos laminates and fabrics in the aeronautics and aerospace industry, a thorough understanding of the behaviour of these materials under various loading conditions is required. The purpose of this work aims to assess the failure of different composite materials subjected to a bending load, using the progressive damage approach. Puck’s failure criteria and gradual degradation model have been used to simulate the initial and the successive damage, respectively. A user-defined material (UMAT) subroutine has been developed and implemented through finite element software Abaqus. Moreover, the effect of geometrical parameters is performed and identified by the experimental protocol. The predicted results obtained by this numerical modelling show a good correlation with the findings of the experimental test.
为了在航空航天工业中开发连续纤维复合材料层压板和织物,需要对这些材料在各种载荷条件下的性能有透彻的了解。这项工作的目的是评估不同的复合材料在弯曲载荷下的失效,使用渐进损伤方法。采用Puck失效准则和逐步退化模型分别模拟了初始损伤和连续损伤。通过有限元软件Abaqus开发并实现了用户自定义材料(UMAT)子程序。此外,通过实验方案对几何参数的影响进行了验证。数值模拟的预测结果与试验结果有较好的相关性。
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引用次数: 0
Effect of surface modification and sodium dodecyl sulfate (SDS) on thermal properties of PMMA/SWCNT nanocomposites 表面改性和十二烷基硫酸钠对PMMA/ swcnts纳米复合材料热性能的影响
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-18 DOI: 10.1080/14658011.2023.2247732
Ersin Yanmaz, M. Doğan
ABSTRACT In this study, the single-walled carbon nanotube (p-SWCNTs) and poly (methyl methacrylate) (PMMA) polymer nanocomposites were prepared by solution casting method. The effects of functionalization and sodium dodecyl sulfate (SDS) on the thermal properties of PMMA/p-SWCNT nanocomposites were investigated. Samples were characterised using BET, FTIR-ATR, SEM, DTA/TG, DSC, TEM and AFM. Morphological analyses showed that changes in the structure of SWCNTs with modification occurred and CNTs were tubular structure, homogeneously dispersed and nano-sized. Functionalised SWCNTs increased the first mass loss (Tmax1), the second mass loss (Tmax2) and glass transition temperatures (Tg) of PMMA. SDS assisted both better dispersion of CNTs and interaction between PMMA and CNTs. While PMMA/p-SWCNT-OH (0.1 wt.%) had the highest thermal stability in SDS-free medium, PMMA/SDS/p-SWCNT-O-APTS (0.1 wt.%) had the highest thermal stability in SDS medium. The maximum increases at Tmax1 and Tmax2 temperatures of nanocomposites were calculated as 49 and 13°C for PMMA/SDS/p-SWCNT-O-APTS (0.1 wt.%), respectively.
摘要本研究采用溶液浇铸法制备了单壁碳纳米管(p-SWCNTs)和聚甲基丙烯酸甲酯(PMMA)聚合物纳米复合材料。研究了功能化和十二烷基硫酸钠(SDS)对PMMA/p- swcnts纳米复合材料热性能的影响。采用BET、FTIR-ATR、SEM、DTA/TG、DSC、TEM和AFM对样品进行表征。形态学分析表明,改性后的SWCNTs结构发生了变化,CNTs呈管状结构,分布均匀,呈纳米级。功能化的SWCNTs增加了PMMA的第一次质量损失(Tmax1)、第二次质量损失(Tmax2)和玻璃化转变温度(Tg)。SDS有助于CNTs更好的分散和PMMA和CNTs之间的相互作用。PMMA/p-SWCNT-OH (0.1 wt.%)在无SDS介质中热稳定性最高,PMMA/SDS/p-SWCNT-O-APTS (0.1 wt.%)在SDS介质中热稳定性最高。PMMA/SDS/p- swcnts - o - apts在Tmax1和Tmax2温度下的最大增幅分别为49°C和13°C (0.1 wt.%)。
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引用次数: 0
Evaluation of waste polyethylene terephalate in polyol and polyurethane production 废聚对苯二甲酸乙二醇酯在多元醇和聚氨酯生产中的应用评价
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-08-16 DOI: 10.1080/14658011.2023.2238337
Tülay Fırat, F. Kar
ABSTRACT As technology advances and human population grows, we must meet our diverse needs while minimising harm to the environment. One solution is to prioritise recycling and using second-hand consumer goods. In this study, PET flakes were depolymerised by glycolysis using different molar ratios of glycol such as propylene glycol(PG), triethylene glycol(TEG) and polyethylene glycol(PEG 400) in the presence of two different catalysts: zinc acetate- zinc sulphate. As a result, glycated products (polyols-PO) were obtained. The obtained polyols were then used to synthesise polyurethane films (PU) via acetone process. The thermal and chemical characterisations of the polyurethane films (PU) were analysed. In similar studies, zinc acetate was used as a transesterification catalyst for the glycolysis process. In this study, the same process was carried out using zinc sulphate and zinc acetate. Zinc sulphate was found to be a cheaper and eco-friendlier catalyst alternative to zinc acetate for the glycolysis process.
随着科技的进步和人口的增长,我们必须在满足人类多样化需求的同时,尽量减少对环境的危害。一个解决方案是优先回收和使用二手消费品。在本研究中,使用不同摩尔比的乙二醇,如丙二醇(PG)、三甘醇(TEG)和聚乙二醇(peg400),在两种不同的催化剂醋酸锌-硫酸锌的存在下,通过糖酵解PET薄片。结果得到糖基化产物(多元醇- po)。然后用丙酮法合成聚氨酯薄膜(PU)。分析了聚氨酯薄膜的热、化学特性。在类似的研究中,乙酸锌被用作糖酵解过程的酯交换催化剂。在本研究中,采用硫酸锌和乙酸锌进行了相同的工艺。在糖酵解过程中,硫酸锌是一种更便宜、更环保的催化剂,可以替代醋酸锌。
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引用次数: 0
Lifetime prediction under dead-load long-term creep test and models analysis of wood-plastic composites for building materials 建筑材料木塑复合材料恒载长期蠕变试验寿命预测及模型分析
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-07-12 DOI: 10.1080/14658011.2023.2232666
T. Ratanawilai, Vira Leelasilapasart, Chainarong Srivabut, S. Ratanawilai
ABSTRACT Optimal formulation of wood-plastic composites (WPCs) from recycled polypropylene (rPP) and rubberwood flour (RWF) was determined. Mechanical properties and long-term creep behaviour of rPP and WPCs were investigated. This study revealed that an increasing of rubberwood flour content clearly increases the flexural, compressive, and tensile values. The modulus of composite samples linearly increased with an increasing amount of RWF. The creep behaviour test with load levels at 20, 30, and 40% of the ultimate flexural strength were conducted for 1000 h. The deflection of the composites at the same load levels of rPP gave the higher creep behaviour (2.45, 4.65, and 6.68 mm) than that of WPCs (1.53, 2.41, and 3.37 mm), respectively. Six-element for determining Burger model parameters was well fitted with the long-term creep of WPCs, this deflection result was compared to four-element Burger and Power law models. Finally, the master curve could predict lifetime of composite materials.
以再生聚丙烯(rPP)和橡胶木粉(RWF)为原料,确定了木塑复合材料(WPCs)的最佳配方。研究了rPP和WPCs的力学性能和长期蠕变行为。本研究表明,橡胶木粉含量的增加明显增加了弯曲、压缩和拉伸值。复合材料的模量随RWF用量的增加而线性增加。在20%、30%和40%的极限抗弯强度荷载水平下进行了1000小时的蠕变行为试验。在相同rPP荷载水平下,复合材料的挠度(2.45、4.65和6.68 mm)比WPCs的挠度(1.53、2.41和3.37 mm)更高。确定Burger模型参数的六元模型较好地拟合了WPCs的长期蠕变,并将该挠度结果与四元Burger和幂律模型进行了比较。最后,主曲线可以预测复合材料的寿命。
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引用次数: 0
Thermal and mechanical properties of carbon-based rubber nanocomposites: a review 碳基橡胶纳米复合材料的热力学性能研究进展
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-07-05 DOI: 10.1080/14658011.2023.2231286
F. Shahamatifard, D. Rodrigue, F. Mighri
ABSTRACT Developing thermally conductive rubber nanocomposites for heat management is a difficult task for many applications, including tires. Even though rubber materials generally have poor thermal conductivity, the addition of various conductive fillers is required to prevent heat accumulation. However, high filler loading has a significant effect on the mechanical properties of the final product. In addition to the role of filler loading, structure, and morphology, various types of functionalization are required to improve the incorporation of the fillers in the rubber matrix. The main objective of this review is to summarise recent investigations on the thermal and mechanical properties of rubber nanocomposites filled with carbon-based particles such as carbon black, carbon nanotubes, and graphene derivatives.
开发用于热管理的导热橡胶纳米复合材料对于包括轮胎在内的许多应用来说是一项艰巨的任务。尽管橡胶材料的导热性一般较差,但需要添加各种导电填料以防止热量积聚。然而,高填充量对最终产品的力学性能有显著影响。除了填料的载荷、结构和形态的作用外,还需要各种类型的功能化来改善填料在橡胶基体中的掺入。本综述的主要目的是总结近年来在填充碳基颗粒(如炭黑、碳纳米管和石墨烯衍生物)的橡胶纳米复合材料的热性能和力学性能的研究。
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引用次数: 2
Enhanced electrochemical pseudocapacitance performance of poly tyramine composite on the surface of polyethylene glycol modified electrode 聚酪胺复合材料在聚乙二醇修饰电极表面的电化学赝电容性能增强
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-11 DOI: 10.1080/14658011.2023.2219085
A. Ehsani, M. Moftakhar
ABSTRACT In the present study, we introduce the first study for investigating the effect of polyethylene glycol (PEG) on the electrochemical performance of the PTy electroactive film. In this work, we applied PEG to improve electrochemical performance of PTy electroactive film. The electrochemical properties of the prepared electrodes were investigated by means of various electrochemical methods including electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV) and consecutive charge/discharge. The developed electrode in this study exhibits a specific capacity of 4200 mF.cm−2 at 5 mA.cm−2 current density while retaining 90% of the initial capacitance after 3000 cycles. Our results provide an improved conductive polymer composite film with high active surface area, ease of synthesis and high cycling stability for supercapacitors (SCs) in aqueous electrolytes. GRAPHICAL ABSTRACT
摘要:本文首次研究了聚乙二醇(PEG)对PTy电活性膜电化学性能的影响。在这项工作中,我们应用聚乙二醇来改善PTy电活性膜的电化学性能。采用电化学阻抗谱(EIS)、循环伏安法(CV)和连续充放电等电化学方法对制备的电极的电化学性能进行了研究。本研究开发的电极具有4200mf的比容量。cm−2在5ma。Cm−2电流密度,同时在3000次循环后保持90%的初始电容。我们的研究结果为超级电容器(SCs)提供了一种具有高活性表面积、易于合成和高循环稳定性的导电聚合物复合膜。图形抽象
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引用次数: 0
Numerical and experimental study of viscoelastic properties and energy absorption of functionally graded negative stiffness honeycomb made of Polyamide 12 聚酰胺12功能梯度负刚度蜂窝粘弹性及吸能特性的数值与实验研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-06-06 DOI: 10.1080/14658011.2023.2219083
M. Shafipour, S. Y. Ahmadi-Brooghani
ABSTRACT This study investigated the effect of a functionally graded negative stiffness (FGNS) honeycomb made from polyamide 12 (PA12) on increasing energy absorption. In addition, the viscoelastic model of PA12 was implemented in the finite element (FE) model to demonstrate the recoverability of these structures. First, a quasi-static compression test was performed on constant thickness negative stiffness (CTNS) honeycomb and FGNS honeycomb. Then, these two structures’ FE models were simulated. The stress relaxation test was utilised to derive Prony series coefficients for PA12 viscoelastic properties. The results of viscoelastic simulation for CTNS and FGNS honeycombs were then compared with experimental results. The comparison demonstrated a good agreement in both the loading and unloading stages. Furthermore, the critical parameters for evaluating the structural energy absorption of the FGNS honeycomb and the conventional ones were used in this study. According to the results, the FGNS honeycomb outperformed the CTNS experimentally and numerically.
摘要:本研究研究了聚酰胺12 (PA12)制成的功能梯度负刚度(FGNS)蜂窝对增加能量吸收的影响。此外,在有限元(FE)模型中实施了PA12的粘弹性模型,以证明这些结构的可恢复性。首先,对恒厚负刚度(CTNS)蜂窝和FGNS蜂窝进行了准静态压缩试验。然后,对这两种结构的有限元模型进行了仿真。利用应力松弛试验,推导了PA12粘弹性的proony级数系数。将CTNS和FGNS蜂窝的粘弹性模拟结果与实验结果进行了比较。对比结果表明,在加载和卸载阶段均具有较好的一致性。此外,本研究还采用了评价FGNS蜂窝结构吸能的关键参数和常规参数。实验和数值结果表明,FGNS蜂窝的性能优于CTNS。
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引用次数: 0
Mechanical and tribological properties of chemically modified jute/epoxy composites 化学改性黄麻/环氧复合材料的力学和摩擦学性能
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-15 DOI: 10.1080/14658011.2023.2212325
S. Behera, Rakesh Kumar Gautam, S. Mohan, Arghya Chattopadhyay
ABSTRACT The purpose of the present work is to assess the effectiveness of low-cost and environmental friendly chemical modification of jute fibres based on the usage of sodium hydroxide (AT), sodium carbonate (ST) and sodium hydrogen carbonate (SHT) on the morphological, water absorption, mechanical and tribological characteristics of jute fibre-reinforced epoxy composites (JFREC). Mechanical properties like tensile strength, tensile modulus and impact strength showed appreciable improvement for the AT JFREC (38.08%, 30.56% and 31.66%), ST JFREC (70.03%, 33.06% and 41.30%) and SHT JFREC (24.69%, 8.88% and 22.61%) when compared to untreated JFREC. The experimental results also confirmed that the improved fibre-matrix adhesion, attained by chemical modification, increased the water absorption resistance and the tribological properties of chemically modified JFREC. Improved mechanical and tribological properties attained by the chemically modified JFREC can be found as a potential application in automotive and packaging industries.
摘要本研究的目的是评估基于氢氧化钠(AT)、碳酸钠(ST)和碳酸氢钠(SHT)的低成本、环保的黄麻纤维化学改性对黄麻纤维增强环氧复合材料(JFREC)形态、吸水率、力学和摩擦学特性的有效性。与未经处理的JFREC相比,AT JFREC(38.08%、30.56%和31.66%)、ST JFREC(70.03%、33.06%和41.30%)和SHT JFREC(24.69%、8.88%和22.61%)的抗拉强度、抗拉模量和冲击强度等力学性能均有明显改善。实验结果还证实,化学改性后的JFREC与纤维基体的粘附性得到改善,从而提高了JFREC的吸水性和摩擦学性能。通过化学改性的JFREC获得了更好的机械和摩擦学性能,可以在汽车和包装工业中找到潜在的应用。
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引用次数: 0
Comparative study on the impact response of polypropylene and epoxy matrix composites with respect to the plate thickness 聚丙烯基与环氧基复合材料冲击响应随板厚的对比研究
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-14 DOI: 10.1080/14658011.2023.2212314
V. Arıkan
ABSTRACT In this study, E-glass fibre-reinforced polypropylene and epoxy matrix composites were produced in different thicknesses and subjected to low-velocity impact tests with 30 joules of energy. The tests yielded force, displacement and energy data, which were used to analyse the effects of thickness variation on impact performance in composite plates with different matrix structures. The results showed that thickness variation creates different impact responses in composites with different matrix materials.
本研究制备了不同厚度的e-玻璃纤维增强聚丙烯和环氧基复合材料,并进行了30焦耳能量的低速冲击试验。试验获得了力、位移和能量数据,用于分析厚度变化对不同基体结构复合材料板冲击性能的影响。结果表明,厚度变化对不同基体材料复合材料的冲击响应有不同的影响。
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引用次数: 0
Preparation and interfacial properties of functionalised graphene oxide modified carbon fibre/epoxy resin matrix composites 功能化氧化石墨烯改性碳纤维/环氧树脂基复合材料的制备及其界面性能
IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-05-09 DOI: 10.1080/14658011.2023.2207059
Longchun Liu, Sen Liang, Changsheng Zheng, Depan Wang, Yuesong Zhou
ABSTRACT The interfacial properties of carbon fibre (CF) reinforced epoxy resin composites are the key factors affecting the mechanical properties of the materials. To improve the interfacial adhesion between CF and epoxy resin, an effective CF surface modification method is proposed in this paper. The surface of graphene oxide (GO) was functionalised with 3-aminopropyltriethoxysilane (APTES), and then the functionalised graphene oxide (FGO) was grafted on the surface of CF. The surface roughness of modified CF was significantly improved by the SEM experiment. The effectiveness of grafting was verified by FTIR and XPS, and the chemical functional groups on the surface of modified CF were increased. The microstructure of the failure interface of the composites was observed, the modification did not reduce the tensile strength of CF, and the interlaminar shear strength (ILSS) of modified CF/ epoxy resin composite was increased by 39.91%. It was found that the CF modified by FGO was beneficial to the improvement of the interface properties of CF/epoxy resin composite. This has positive academic significance for improving the interfacial and mechanical properties of CF composites.
碳纤维增强环氧树脂复合材料的界面性能是影响材料力学性能的关键因素。为了提高CF与环氧树脂的界面附着力,本文提出了一种有效的CF表面改性方法。用3-氨基丙基三乙氧基硅烷(APTES)对氧化石墨烯(GO)表面进行功能化处理,然后将功能化后的氧化石墨烯(FGO)接枝到CF表面,SEM实验结果表明,改性后的CF表面粗糙度明显提高。FTIR和XPS验证了接枝的有效性,改性后的CF表面的化学官能团有所增加。对复合材料破坏界面的微观结构进行了观察,改性并未降低CF的抗拉强度,改性后CF/环氧树脂复合材料的层间剪切强度(ILSS)提高了39.91%。结果表明,FGO改性的CF有利于CF/环氧树脂复合材料界面性能的改善。这对改善CF复合材料的界面性能和力学性能具有积极的学术意义。
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引用次数: 0
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