Electrical Properties of 'Water in Castor Oil' Emulsion

I. Nazarenko, O. Didenko, A. Loboda, R. Kushlyk, L. Chervinsky
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Abstract

The results of the research into the electrical properties of the "water in castor oil" emulsion, which make it possible to substantiate the technology of castor oil purification from plant impurities and water in an electric field, were presented.

The experimental studies of the electrical properties of the "water in castor oil" emulsion revealed the dependences of specific resistance to direct and alternating currents and dielectric loss angle tangent on the temperature and water content. It was proved that the active component of specific resistance to the suspension "water in castor oil" on AC is smaller than resistance to DC. That is why, at the temperature of 80 °C and water content of 2 %, heat release on AC is 10 % higher than the heat release on DC. According to this, it is advisable to perform the process of castor oil purification from plant impurities and water residues on AC. This makes it possible to obtain additional heat release and thereby compensate for heat losses for the vaporization of flotation bubbles, which leads to the stable process of flotation purification. A comparison of the magnitudes of polarization losses and losses of end-to-end electrical conductivity for pure oil indicates their identical order. The addition of water leads to an increase in polarization losses due to the structural and dipole polarization of water as a polar fluid. Due to this, from the theoretical point of view, it can be argued about additional local heat release on finely dispersed water drops in the quantity, which can ensure the compensation for the heat needed for vaporization. According to this, vaporization does not require indirect heating of the electrode area from an external source at the expense of thermal conductivity.

The obtained results of the experimental research make it possible to substantiate the technological and structural parameters of the electro-technological complex of castor oil purification in the electric field of the cylindrical system of electrodes.
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“蓖麻油中水”乳化液的电学性质
本文介绍了“蓖麻油中水”乳液电学性质的研究结果,为蓖麻油在电场条件下从植物杂质和水中提纯蓖麻油的技术提供了理论依据。通过对蓖麻油中水乳液电学性能的实验研究,揭示了乳液的直流、交流比电阻和介电损耗角正切与温度和含水量的关系。结果表明,活性组分对悬浮液“蓖麻油中水”在交流上的比电阻小于对直流的比电阻。这就是为什么在温度为80℃,含水量为2%的情况下,交流电放出的热量比直流电放出的热量高10%。因此,建议将蓖麻油从植物杂质和水渣中提纯,在AC上进行。这样可以获得额外的放热,从而补偿浮选气泡汽化的热损失,使浮选纯化过程稳定。对纯油的极化损耗和端到端电导率损耗的比较表明它们的量级相同。由于水作为极性流体的结构极化和偶极极化,水的加入导致极化损失的增加。因此,从理论的角度来看,可以认为在量中存在分散细密的水滴的额外局部放热,可以保证汽化所需热量的补偿。根据这一点,汽化不需要从外部源间接加热电极区域,以牺牲导热性为代价。实验研究的结果为在圆柱形电极系统的电场中确定蓖麻油净化电工艺复合物的工艺参数和结构参数提供了可能。
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