Pengaruh Konsentrasi Surfaktan Non-Ionik Terhadap Viskositas Perekat Polivinil Asetat Berbasis Air

R. Sihombing, Robby Sudarman, Agustinus Ngatin
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Abstract

Substrate combining could be done by using adhesive. In Indonesia, especially industrial field, solvent base adhesives were still being developed. This kind of adhesive was not environmental friendly and not safe handling. Therefore, Polyvinyl Acetate (PVAc) water-based adhesive was prepared as an outcome of this research as one of solution to overcome the problem above. Effect of surfactant concentration on the viscosity was aimed at this research. Semi continuous polymerization with stirring motor rates on 50 – 500 rpm was used (optional).  Pressure of 1 atm, 750C temperature, 5 – 6 hours reaction time for each was used as polymerization operation in this research. Vinyl Acetate Monomer (VAM), partial hydrolysis Polyvinyl Alcohol (PVOH), water, Ammonium Persulfate (APS) were prepared as raw material. NP-10 and NP-06 were non-ionic surfactants which each concentration was varied in this research. Water-based adhesive with NP-06 concentration variation resulting in viscosity from 98 m.Pa for 0.17 %wt concentration to 213 m.Pa for  0.68 %wt concentration. While NP-10 concentration variation resulting viscosity from 143 m.Pa for 0.17 %wt to 321 m.Pa for 0.68 %wt concentration. Therefore, adhesive with NP-10 surfactant concentration variable has a higher viscosity rate than NP-06 ones. Keywords: Water-based adhesive, non-ionic surfactant, adhesive viscosity
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非离子丝质浓度对水基丙烯酸聚乙烯粘胶的影响
基材的结合可以用粘合剂来完成。在印度尼西亚,特别是工业领域,溶剂型胶粘剂仍处于开发阶段。这种胶粘剂不环保,处理不安全。因此,本研究的成果是制备聚醋酸乙烯酯(PVAc)水性胶粘剂,作为克服上述问题的解决方案之一。以表面活性剂浓度对粘度的影响为研究对象。采用半连续聚合,搅拌电机转速为50 - 500 rpm(可选)。本研究采用压力为1atm,温度为750C,每次反应时间为5 ~ 6h的聚合操作。以乙酸乙烯酯单体(VAM)、部分水解聚乙烯醇(PVOH)、水、过硫酸铵(APS)为原料制备。NP-10和NP-06为非离子型表面活性剂,不同浓度的表面活性剂在本研究中有所不同。水性胶粘剂与NP-06浓度变化导致粘度从98 m。Pa为0.17%,wt浓度为21.3 m。Pa为0.68% wt浓度。而NP-10浓度变化导致粘度从143 m。Pa为0.17%,wt为321 m。Pa为0.68% wt浓度。因此,表面活性剂浓度为NP-10的胶粘剂比表面活性剂浓度为NP-06的胶粘剂具有更高的黏度。关键词:水基胶粘剂,非离子表面活性剂,胶粘剂粘度
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