Computation of Thermoacoustic and Thermodynamic Properties of Aqueous Methyl Orange Solution from Density and Sonic Speed Data

J. D. Pandey, R. Sethi, S. C. Shrivastava, Vandna Pathak, S. Vishwakarma
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Abstract

Density and ultrasonic speed data have been used to calculate a number of useful and important thermoacoustic and thermodynamic parameters such as thermal expansivities, α, isothermal compressibility, βT, internal pressure, Pint, specific heat ratio, Υ, surface tension, σ, Pseudo-Grüneisen parameter, Г, non-linearity parameter, B/A, by empirical relations at T= (303, 308, 313 and 318) K temperatures in the range concentration from 0.05 to 1 molar. Solvation number, Sn, has been computed to support the conformational change in geometry of aqueous methyl orange solution. The calculated values highly support the change in orientation and abnormal behavior of methyl orange solution at varying concentrations and quite satisfactory results are obtained.
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从密度和声速数据计算甲基橙水溶液的热声和热力学性质
密度和超声速度数据已被用来计算一些有用的和重要的热声和热力学参数,如热膨胀率,α,等温压缩率,βT,内压,Pint,比热比,Υ,表面张力,σ,伪grisen参数,Г,非线性参数,B/ a,由经验关系在T=(303, 308, 313和318)K的浓度范围从0.05到1mol / l。通过计算溶剂化数Sn来支持甲基橙水溶液的几何构象变化。计算值高度支持甲基橙溶液在不同浓度下的取向变化和异常行为,得到了令人满意的结果。
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