Synthesis, Spectroscopic and Antimicrobial of New Cr(III), Co(II), Ni(II) and Cu(II) Schiff Base Complexes

Huda E.M. Amin, O. Ali, Samir M. EL-Medania, A. S. Sayed
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Abstract

Schiff bases are condensation products of primary amine and aliphatic or aromatic carbonyl compounds with the general formula (RCH=N-R), that makes the schiff base a stable imine. The linkage azomethine group contains a pair of π electrons bonded between carbon and nitrogen (CH=N-). In addition, the nitrogen atom present in the azomethine group has a lone pair of electron and this add distinct properties to this group. Schiff bases derived from aromatic amines and aromatic aldehydes have a wide variety of applications in many fields, eg., biological [1-4], Heterogenous catalyst [5], oxidation of alkanes [6], catalytic applications [7,8] and photo luminescent properties [9,10].
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新型Cr(III)、Co(II)、Ni(II)和Cu(II)席夫碱配合物的合成、光谱和抗菌性能
席夫碱是伯胺与脂肪族或芳香羰基化合物的缩合产物,其通式(RCH=N-R)使席夫碱成为稳定的亚胺。联键亚甲基包含一对π电子在碳和氮之间键合(CH=N-)。此外,存在于亚甲基中的氮原子有一对孤电子,这给这个基团增加了独特的性质。由芳香胺和芳香醛衍生的希夫碱在许多领域有着广泛的应用。,生物[1-4],多相催化剂[5],烷烃氧化[6],催化应用[7,8]和光发光性质[9,10]。
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