Solid‐state NMR study of cyclo‐olefin copolymer (COC)

Wu-Jang Huang, F. Chang, P. P. Chu
{"title":"Solid‐state NMR study of cyclo‐olefin copolymer (COC)","authors":"Wu-Jang Huang, F. Chang, P. P. Chu","doi":"10.1002/1099-0488(20001001)38:19<2554::AID-POLB70>3.0.CO;2-#","DOIUrl":null,"url":null,"abstract":"In this article, we have applied solid-state 13C NMR techniques, cross-polarization/magic-angle spinning (CP/MAS), and single-pulse 13C NMR to characterize the NB conformation of the cyclo-olefin copolymer. The copolymers containing higher NB contents produce more NB blocks according to 13C CP/MAS spectral analysis. In addition, NB-dyad-based conformations are able to induce peak splitting in the region of 49–52 ppm. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2554–2563, 2000","PeriodicalId":16853,"journal":{"name":"Journal of Polymer Science. Part B, Polymer Physics","volume":"150 1","pages":"2554-2563"},"PeriodicalIF":0.0000,"publicationDate":"2000-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science. Part B, Polymer Physics","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/1099-0488(20001001)38:19<2554::AID-POLB70>3.0.CO;2-#","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 8

Abstract

In this article, we have applied solid-state 13C NMR techniques, cross-polarization/magic-angle spinning (CP/MAS), and single-pulse 13C NMR to characterize the NB conformation of the cyclo-olefin copolymer. The copolymers containing higher NB contents produce more NB blocks according to 13C CP/MAS spectral analysis. In addition, NB-dyad-based conformations are able to induce peak splitting in the region of 49–52 ppm. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 38: 2554–2563, 2000
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
环烯烃共聚物(COC)的固体核磁共振研究
在本文中,我们采用固态13C NMR技术、交叉极化/魔角旋转(CP/MAS)和单脉冲13C NMR来表征环烯烃共聚物的NB构象。13C CP/MAS谱分析表明,NB含量越高的共聚物产生的NB嵌段越多。此外,基于铌二元的构象能够在49-52 ppm区域诱导峰分裂。©2000 John Wiley & Sons, Inc[J] .高分子材料学报,2003,19 (2):559 - 563
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
5.90
自引率
0.00%
发文量
0
审稿时长
2.1 months
期刊介绍: Since its launch in 1946 by P. M. Doty, H. Mark, and C.C. Price, the Journal of Polymer Science has provided a continuous forum for the dissemination of thoroughly peer-reviewed, fundamental, international research into the preparation and properties of macromolecules. From January 2020, the Journal of Polymer Science, Part A: Polymer Chemistry and Journal of Polymer Science, Part B: Polymer Physics will be published as one journal, the Journal of Polymer Science. The merged journal will reflect the nature of today''s polymer science research, with physics and chemistry of polymer systems at the heart of the scope. You can continue looking forward to an exciting mix of comprehensive reviews, visionary insights, high-impact communications, and full papers that represent the rapid multidisciplinary developments in polymer science. Our editorial team consists of a mix of well-known academic editors and full-time professional editors who ensure fast, professional peer review of your contribution. After publication, our team will work to ensure that your paper receives the recognition it deserves by your peers and the broader scientific community.
期刊最新文献
Quantitative Image Analysis of Fractal‐Like Thin Films of Organic Semiconductors Polymer Physics: A Molecular Approach Abstraction of biochemical reaction systems on polytopes Nonlocal electron-phonon coupling. Influence on the nature of polarons [refereed] Nanocomposites of polyurethane with various organoclays: Thermomechanical properties, morphology, and gas permeability* This paper is dedicated to Prof. Jung Il Jin of Korea University, Seoul Korea, on the occasion of his 60th birthday.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1