Effect of amphiphilic copolymers of oligo(ethylene glycol)methacrylates on the synthesis of N-(dibutylaminomethyl)methacrylamide in an aqueous-organic emulsion

I. R. Arifullin, O. Kazantsev, M. V. Savinova, E. A. Lapteva, V. A. Komarov, M. N. Chubenko
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Abstract

The accelerating effect of adding a low molecular weight sulfonic acid surfactant (alkylbenzenesulfonic acid) and nonionic or containing sulfonic acid units amphiphilic copolymers of methoxy- and higher alkoxyoligo(ethylene glycol)methacrylates on the synthesis of a promising cationic monomer, N-(dibutylaminomethyl)methacrylamide, proceeding in an aqueous-amine emulsion, by the Mannich reaction, was revealed. The infl uence of the concentration of additives and the structure of copolymers on the catalytic effect is shown.
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低聚(乙二醇)甲基丙烯酸酯两亲共聚物对有机水乳液中N-(二丁基氨基甲基)甲基丙烯酰胺合成的影响
研究了在水胺乳液中加入低分子量磺酸表面活性剂(烷基苯磺酸)和非离子型或含磺酸单元的甲氧基低聚(乙二醇)甲基丙烯酸酯两亲共聚物对阳离子单体N-(二丁基氨基甲基)甲基丙烯酰胺合成的促进作用。考察了助剂浓度和共聚物结构对催化效果的影响。
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