Characterization of Impurities and Inclusions in Ferrochrome Alloy and Their Effects on the Inclusion Characteristics in Stainless Steels

Yong Wang, A. Karasev, Wangzhong Mu, J. Park, P. Jönsson
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Abstract

Laboratory scale alloying experiments were carried out by the addition of a commercial low carbon ferrochrome (LCFeCr) alloy to 430-grade ferritic stainless steel. The inclusions in FeCr alloys as well as in the steel samples before and after alloy addition were investigated using an electrolytic extraction (EE) technique. The results show that the Ti content decreases after the FeCr alloy addition. MnCr2O4 inclusions from FeCr alloys are transformed into Ti2O3-Cr2O3 based liquid inclusions and Ti2O3-rich solid inclusions. They are formed due to the reactions between MnCr2O4 and either TiN or dissolved Ti, which needs to be further studied. The ratio of Ti/Al in the steel melt has a direct influence on the evolution of the inclusions. The present study aims to contribute for understanding the impurities in FeCr alloys and their effect on the inclusion characteristics for the stainless steel production.
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铬铁合金中杂质和夹杂物的表征及其对不锈钢夹杂物特性的影响
通过在430级铁素体不锈钢中加入低碳铬铁(LCFeCr)合金,进行了实验室规模的合金化实验。采用电解萃取(EE)技术研究了加入合金前后铁铁合金和钢样品中的夹杂物。结果表明:加入FeCr合金后,Ti含量降低;FeCr合金中MnCr2O4夹杂物转变为基于Ti2O3-Cr2O3的液体夹杂物和富含ti2o3的固体夹杂物。它们是由MnCr2O4与TiN或溶解Ti反应形成的,需要进一步研究。钢熔体中Ti/Al的比例对夹杂物的演化有直接影响。本研究旨在为了解铁铁合金中的杂质及其对不锈钢生产中夹杂物特性的影响作出贡献。
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