Re-reporting the Crystal Structure of Copper Complex from Another Point of View

T. Akitsu, Shintaro Suda, Natsuki Katsuumi
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Abstract

We faced an example of re-reporting of the crystal structure, which was studied from another perspective. With the development of data-driven science, the efficiency of all researchers may be improved if the rules of data "reuse", which are different from "novelty", are established. In this context, the crystal structure of a copper(II) complex with 2,6-pyridine dicarboxylic acid, C14H8O8CuN2.H2O (monohydrate), was re-determined by us again. It has a different number of crystalline water molecules in a crystal of the same copper(II) complex previously reported (trihydrate). Interestingly, both crystal structures have been reported again and again by many researchers for a long time. What’s novelty for each report?
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从另一个角度重新报道铜配合物的晶体结构
我们面对一个晶体结构的重新报道的例子,这是从另一个角度来研究的。随着数据驱动科学的发展,建立不同于“新颖性”的数据“重用性”规则,可以提高所有科研人员的工作效率。在这种情况下,铜(II)与2,6-吡啶二羧酸配合物C14H8O8CuN2的晶体结构。H2O(一水合物),我们又重新测定了。在先前报道的相同的铜(II)配合物(三水合物)晶体中有不同数量的结晶水分子。有趣的是,长期以来,这两种晶体结构都被许多研究人员一次又一次地报道。每个报告的新奇之处是什么?
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