{"title":"Electrochemical inclusion of copper and iron species in a conducting polymer observed in situ using time-resolved X-ray absorption spectroscopy","authors":"D. Guay, G. Tourillon, A. Fontaine","doi":"10.1039/DC9908900041","DOIUrl":null,"url":null,"abstract":"A comparative in situ time-resolved X-ray absorption study of the electrochemical inclusion of copper and iron species in poly(3-methyl-thiophene)(PMeT) is reported. For both treatments, incorporation of metallic ion and complexation with sulphur atoms of the polymer backbone lead to a significant increase of the ex situ macroscopic conductivity. However, the detailed mechanisms and kinetics of the various processes are specific to the metallic ion incorporated in the polymer.","PeriodicalId":12210,"journal":{"name":"Faraday Discussions of The Chemical Society","volume":"21 1","pages":"41-50"},"PeriodicalIF":0.0000,"publicationDate":"1990-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"9","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Faraday Discussions of The Chemical Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/DC9908900041","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 9
Abstract
A comparative in situ time-resolved X-ray absorption study of the electrochemical inclusion of copper and iron species in poly(3-methyl-thiophene)(PMeT) is reported. For both treatments, incorporation of metallic ion and complexation with sulphur atoms of the polymer backbone lead to a significant increase of the ex situ macroscopic conductivity. However, the detailed mechanisms and kinetics of the various processes are specific to the metallic ion incorporated in the polymer.
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