Polyethylene terephthalate recycling for food-contact applications: testing, safety and technologies: a global perspective

F. Bayer
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引用次数: 67

Abstract

Studies were undertaken to determine the composition of five different types of post-consumer polyethylene terephthalate (PET) feedstreams to ascertain the relative amounts of food containers and non-food containers. Deposit post-consumer PET feedstreams contained ~100% food containers, whereas curbside feedstreams contained from 0.04 to 6% non-food containers. Analysis of the PET containers from the different type feedstreams after the containers were subjected to a commercial PET wash system and after processing with a proprietary decontamination technology was accomplished to determine the levels of compounds in the post-consumer PET after the various stages of processing. Comprehensive thermal desorption/GC/MS, purge and trap GC/MS purge and trap GC quantitation, PET dissolution and extraction GC analysis and PET dissolution HPLC analysis established the types and concentrations of compounds that absorb in the PET from the various types of postconsumer feedstreams. A total of 121 compounds were identified in the five different feedstreams. The concentration of absorbed compounds remaining in the deposit material and the non-food applications material after the commercial wash was 28 and 39mgkg -1 respectively. Analysis of the feedstreams after subjecting the material to a proprietary decontamination process demonstrated the ability of removing all the absorbed compounds to a level below the level of the threshold of regulation. The safety of sourcing of post-consumer PET from food use applications verses non-food use applications of PET has been established.
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食品接触应用的聚对苯二甲酸乙二醇酯回收:测试,安全和技术:全球视角
研究确定了五种不同类型的消费后聚对苯二甲酸乙二醇酯(PET)原料流的组成,以确定食品容器和非食品容器的相对数量。沉积物消费后PET饲料流包含~100%的食品容器,而路边饲料流包含0.04%至6%的非食品容器。在经过商用PET洗涤系统和专有去污技术处理后,对来自不同类型进料流的PET容器进行分析,以确定经过不同处理阶段后消费后PET中的化合物水平。综合热解吸/GC/MS,吹扫和捕集GC/MS吹扫和捕集GC定量,PET溶出和萃取,GC分析和PET溶出HPLC分析确定了从各种消费后的原料流中吸收到PET中的化合物的类型和浓度。在5种不同的进料流中共鉴定出121个化合物。经商业洗涤后,沉淀物料和非食品应用物料中残留的吸收化合物浓度分别为28和39mgkg -1。在对材料进行专有的净化处理后,对进料流进行分析,证明了将所有吸收的化合物去除到低于规定阈值水平的能力。从食品应用中采购消费后PET与非食品应用中采购PET的安全性已经确定。
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