F. Allouche, V. Mougel, Wolfram R. Grüning, C. Copéret
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引用次数: 4
Abstract
Attempt to synthesize a bis-thiolate tungsten alkylidene catalysts with bulky arenethiolates unexpectedly yielded upon activation of DME a pentacoordinated complex of general formula [W(NAr)(CHCMe3 )(SAr’)(κ 2 -O-CH2 -CH2 -OMe)], which is active towards self-metathesis of cis-4-nonene compared to the parent bis-benzenethiolate.
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