Analysis of Cu(In,Ga)Se2 grading evolution during low deposition temperature co-evaporation process by GD-OES and XPS measurements. Impact on solar cell performances and modelling

V. Achard, S. Béchu, M. Balestrieri, M. Bouttemy, M. Jubault, A. Etcheberry, D. Lincot, F. Donsanti
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Abstract

One of the key parameters to achieve high efficiency Cu(In,Ga)Se2 (CIGS) solar cells is the proper control of Ga grading. From previous results, by using bulk material characterization, a first assessment of the CIGS growth on polyimide foils at low temperature was performed. Moreover, a maximum efficiency of 17.8% has been achieved with steep Ga grading. Here, a first step to the establishment of a growth model of CIGS grown at low temperature is proposed by coupling surface and volume characterization. Then, simulation of the photovoltaic performances of the cell is used to complete experimental observations and to explain the beneficial effect of steep Ga grading.
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低温共蒸发过程中Cu(In,Ga)Se2级配演化的GD-OES和XPS分析对太阳能电池性能和建模的影响
实现高效Cu(In,Ga)Se2 (CIGS)太阳能电池的关键参数之一是正确控制Ga的分级。根据先前的结果,通过使用大块材料表征,首次评估了低温下聚酰亚胺箔上CIGS的生长。此外,陡坡Ga级配的效率最高可达17.8%。本文提出了通过表面和体积耦合表征来建立低温生长CIGS模型的第一步。然后,通过对电池光伏性能的模拟来完成实验观察,并解释陡峭Ga级配的有益效果。
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