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2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)最新文献

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Unintentional Islanding Evaluation Utilizing Discrete RLC Circuit Versus Power Hardware-in-the Loop Method 利用离散RLC电路与电源在环硬件方法的非故意孤岛评估
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198986
S. Gonzalez, Edgardo Desardén-Carrero, Nicholas S. Gurule, Erick E. Aponte-Bezares
The high penetration of photovoltaic (PV) distributed energy resources (DER) facilitates the need for today’s systems to provide grid support functions and ride-through voltage and frequency events to minimize the adverse impacts on the distribution power system. These new capabilities and its requirements have created concerns that autonomous unintentional islanding (UI) algorithms are not sufficient to prevent a condition were the loss of utility is detected. Type tests in IEEE 1547-2018 have evolved to thoroughly evaluate DER capabilities and a new method includes power hardware-in-the-loop (PHIL) testing. Sandia National Laboratories is performing a detailed laboratory comparison of the tuned Resistive, Inductive, Capacitive (RLC) circuit method using discrete elements and the PHIL that applies the PV inverter equipment under test (EUT), real-time simulator, and a power amplifier. The PHIL method allows UI assessments without the need for potentially expensive, large, heat generating discrete loads.
光伏(PV)分布式能源(DER)的高渗透率促进了当今系统提供电网支持功能和穿越电压和频率事件的需求,以最大限度地减少对配电系统的不利影响。这些新功能及其需求引发了人们的担忧,即自动无意孤岛(UI)算法不足以防止检测到效用损失的情况。IEEE 1547-2018中的类型测试已经发展到彻底评估DER能力,并采用了一种新的方法,包括电源硬件在环(PHIL)测试。桑迪亚国家实验室正在对使用离散元件的调谐电阻、电感、电容(RLC)电路方法和应用PV逆变器被测设备(EUT)、实时模拟器和功率放大器的PHIL进行详细的实验室比较。PHIL方法允许UI评估,而不需要潜在昂贵的、大型的、产生热量的离散负载。
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引用次数: 2
Realizing Perovskite Solar Cells on Roll Roll-to-Roll Compatible Processes 实现钙钛矿太阳能电池的卷对卷兼容工艺
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198957
Amir H. Ghahremani, T. Druffel
The promising growth of Organic-inorganic perovskite solar cells (PSCs) efficiency and durability has led to development and research towards commercialization through high throughput automated manufacturing of these photovoltaic (PV) devices. Rapid thermal annealing of the deposited metal oxide layers and the photoactive layer, along with the use of additives, can potentially diminish device fabrication time and enhance device performance through improved thin film characteristics. Applying millisecond pulses of energetic light can form high-quality morphology for the transparent conductive oxide electron transport layer as well as the perovskite absorber film. It was observed that the addition of an alkyl halide, such as diiodo methane (CH2I2), to the perovskite photoactive layer could considerably improve the power conversion efficiency (PCE) of the cells through stitching the grain boundaries that act as charge recombination centers. This manuscript spans the material characterization results of the CH2I2 assisted mixed cation perovskite films through Scanning electron microscope (SEM) as well as X-ray diffraction spectroscopy (XRD) techniques. It was observed that the synergy of millisecond pulsed annealing and CH2I2 additive could enhance the PSCs photovoltaic parameters, resulting in an in crease from 6.45 % for the pristine devices to 11.34 % efficiency for the mixed cation PSC with photonic pulsed annealing when processed in the ambient with humidity of about 60%. This manuscript highlights the significance of intense pulsed light on rapid annealing of electron transport thin films as well as the impact of released halide from the alky halide to boost the quality of absorber films, which can be a potential candidate for high throughput automated fabrication of PSC PSCs.
有机-无机钙钛矿太阳能电池(PSCs)的效率和耐用性的有希望的增长导致了通过高通量自动化制造这些光伏(PV)器件的商业化开发和研究。对沉积的金属氧化物层和光活性层进行快速热退火,并使用添加剂,可以通过改善薄膜特性来缩短器件制造时间并提高器件性能。应用毫秒脉冲的高能光可以形成高质量的透明导电氧化物电子传输层和钙钛矿吸收膜的形貌。结果表明,在钙钛矿光活性层中加入烷基卤化物,如二碘甲烷(CH2I2),可以通过拼接晶界作为电荷重组中心,显著提高电池的功率转换效率(PCE)。本文通过扫描电子显微镜(SEM)和x射线衍射光谱(XRD)技术对CH2I2辅助混合阳离子钙钛矿薄膜的材料表征结果进行了综述。研究发现,毫秒脉冲退火和CH2I2添加剂的协同作用可以提高PSCs的光电参数,在湿度约为60%的环境中处理时,光子脉冲退火混合阳离子PSC的效率从原始器件的6.45%提高到11.34%。本文强调了强脉冲光对电子输运薄膜快速退火的重要性,以及从碱性卤化物中释放卤化物对提高吸收膜质量的影响,这可能是高通量自动化制造PSC PSC的潜在候选者。
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引用次数: 1
Accurate Efficiency Measurements for Emerging PV: A Comparison of NREL's Steady-State Performance Calibration Protocol Between Conventional and Emerging PV Technologies 新兴光伏的精确效率测量:NREL在传统和新兴光伏技术之间的稳态性能校准协议的比较
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198951
Tao Song, T. Moriarty, D. Levi
Emerging PV technologies (e.g. Perovskite, and Quantum Dot) are commonly known to possess challenges for accurate performance measurement under the existing IEC 60904 series of standards, which were developed for conventional Si solar cells. Potential performance artifacts depending on scan rates and directions and light bias exposure history are often seen in those emerging solar cells. To avoid these artifacts and provide an unbiased and reliable efficiency measurement, NREL's Cell and Module Performance (CMP) Group has developed a steady-state performance calibration protocol - the asymptotic PMAX method. In this paper, we applied this procedure to four PV cell technologies, Si, CIGS, perovskite, and Quantum Dot (QD), and compared their performance variations between the transient and the steady-state conditions. By comparison, we found that the performance parameters ( i.e. VOC, ISC, FF, η) measured between fast I-V scans (and the asymptotic method (steady-state) change significantly for perovskite and QD cells. These changes do not happen for Si and CIGS cells. Furthermore, the statistical performance analysis on nearly 100 emerging cells received globally (including OPV, Perovskite, and QD) shows that over 70 % of the fast I-V scans have a relative performance deviation larger than 1% compared to those determined using the asymptotic PMAX scan. Given the complex dynamic behavior observed in emerging PV devices, the CMP group at NREL thus only certifies their steady steady-state performance using the Asymptotic PMAX method. We highly recommend similar steady-state performance calibration protocol for all researchers in emerging PV because accuracy in reported efficiencies is critical to the long-term success of those promising new PV technologies.
众所周知,新兴光伏技术(例如钙钛矿和量子点)在现有的IEC 60904系列标准下具有准确测量性能的挑战,这些标准是为传统的硅太阳能电池开发的。在这些新兴的太阳能电池中,经常可以看到潜在的性能伪影,这取决于扫描速率和方向以及光偏置曝光历史。为了避免这些伪像并提供无偏和可靠的效率测量,NREL的电池和模块性能(CMP)小组开发了一种稳态性能校准方案-渐近PMAX方法。在本文中,我们将此过程应用于四种光伏电池技术,Si, CIGS,钙钛矿和量子点(QD),并比较了它们在瞬态和稳态条件下的性能变化。通过比较,我们发现钙钛矿和QD电池在快速I-V扫描(和渐近方法(稳态)之间测量的性能参数(即VOC, ISC, FF, η)发生了显著变化。这些变化不会发生在Si和CIGS细胞中。此外,对全球接收的近100个新兴电池(包括OPV、钙钛矿和QD)的统计性能分析表明,与使用渐近PMAX扫描确定的电池相比,超过70%的快速I-V扫描的相对性能偏差大于1%。鉴于在新兴光伏器件中观察到的复杂动态行为,NREL的CMP小组因此只能使用渐近PMAX方法来证明其稳定稳态性能。我们强烈建议所有新兴光伏研究人员采用类似的稳态性能校准方案,因为报告效率的准确性对这些有前景的新光伏技术的长期成功至关重要。
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引用次数: 2
Ga/(Ga + In) grading effects on ultra-thin (UT) CIGS solar cell 超薄(UT) CIGS太阳能电池Ga/(Ga + In)分级效应
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198972
Wei‐Chao Chen, L. Stolt, M. Edoff
Here, we specifically address device performance in ultra-thin CIGS (UT UT-CIGS) films with thickness around 500 nm by systematically implementing varying in in-depth grading of the GGI (Ga/(Ga+In)ratio). By adjusting the GGI slope, the open circuit voltage can be significantly improved, indicating a reduction of recombination in the quasiquasi-neutral region and at the back contact; the photocarrier collection efficiency over the whole absorption spectrum enhanced significantly with an aggressive GGI profile. Ultimately, a power conversion efficiency of UT-CIGS device over 12% with thickness around 500 nm by carefully applying a an appropriate GGI profile was demonstrated.
在这里,我们通过系统地实现GGI (Ga/(Ga+ in)比)的深度分级,专门研究了厚度约为500 nm的超薄CIGS (UT -CIGS)薄膜的器件性能。通过调节GGI斜率,开路电压可以显著提高,表明准中性区和背触点的复合减少;在整个吸收光谱的光载流子收集效率显著提高与侵略性的GGI剖面。最终,在厚度为500 nm左右的情况下,通过适当的GGI配置,证明了UT-CIGS器件的功率转换效率超过12%。
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引用次数: 6
Ab-initio assessment of new sulfo-iodide compounds as candidate top-cell materials for silicon-based multi-junction tandem solar cells 新型碘化亚砜化合物作为硅基多结串联太阳能电池顶电池候选材料的从头算评估
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198991
R. Patterson, Wenhao Xu, S. Wei, M. Green, X. Hao
New semiconductors having the potential for excellent performance, scalable manufacturing and stability on a 25 year horizon are needed to enable silicon tandem solar cells. Here we explore theoretically a new class of non-toxic sulfoiodide compounds (CuxZnySyIx) has the potential to crystallize with the 4-fold coordinated “adamantine” structure. The band gaps predicted may be suitable for silicon multi-junction tandems. Initial calculations show tolerance to Cu vacancies, which do not appear to lead to deep levels in the band gap. These materials could potentially offer the “best of both worlds,” solution processability like an iodide and improved stability like a sulfide.
硅串联太阳能电池需要具有优异性能、可扩展制造和25年稳定性的新型半导体。在这里,我们从理论上探索了一类新的无毒的硫化物化合物(CuxZnySyIx),它具有4层配位“金刚烷”结构结晶的潜力。所预测的带隙可能适用于硅多结串联。最初的计算显示了对Cu空位的容忍,这似乎不会导致带隙的深度。这些材料可能会提供“两全其美”的效果,像碘化物一样具有溶液可加工性,又像硫化物一样具有更好的稳定性。
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引用次数: 0
Sentaurus Simulation of Monolithic Solar Cells with High Open-Circuit Voltage 高开路电压单片太阳能电池的Sentaurus仿真
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198961
Shujian Xue, A. Augusto, S. Bowden
The integration of multiple solar cells in series in a single wafer increases the output voltage, and reduces the output current. With this new concept we can power small appliances with a single wafer, and if these solar cells are integrated in a larger module the series resistance losses are mitigated. To isolate the individual cells, we space them apart in the wafer. The challenge is to optimize the spacing between cells to balance the short-circuit losses with leakages (narrow spacing). Increasing the surface recombination in the intercell region reduces the effect of leakage current, reducing the spacing between cell leading to higher current. Although initially simulations of monolithic solar cell only have less than 15% of efficiency, the new design can improve the efficiency to over 20%. The new design increased the leakage resistance between the parallel cells which decreased the leakage current to less than 10% of the original value and increase the FF from 58.9% to 79.8%.
将多个太阳能电池串联在一块硅片上,增加了输出电压,减小了输出电流。有了这个新概念,我们可以用一个晶圆为小型电器供电,如果这些太阳能电池集成在一个更大的模块中,串联电阻损失就会减少。为了分离单个细胞,我们将它们在晶圆片中分开。挑战在于优化电池间距,以平衡短路损耗和泄漏(窄间距)。增加电池间区域的表面复合减少了漏电流的影响,减少了电池间距,从而导致更高的电流。虽然单片太阳能电池最初的模拟只有不到15%的效率,但新设计可以将效率提高到20%以上。新设计增加了并联电池之间的漏阻,使漏电流降低到原值的10%以下,并将FF从58.9%提高到79.8%。
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引用次数: 2
Simulation of Grid-Forming Inverters Dynamic Models using a Power Hardware-in-the-Loop Testbed 基于电力半实物试验台的成网逆变器动态模型仿真
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198969
J. Hernandez-Alvidrez, A. Summers, M. Reno, J. Flicker, N. Pragallapati
Modern power grids include a variety of renewable Distributed Energy Resources (DERs) as a strategy to comply with new environmental and renewable portfolio standards (RPSs) imposed by state and federal agencies. Typically, DERs include the use of power electronic (PE) interfaces to interact with the power grid. Recently this interaction has not only been focused on supplying maximum available energy, but also on supporting the power grid under abnormal conditions such as low voltage/frequency conditions or non-unity power factor. Over the last few years, grid-following inverters (GFLIs) have proven their value while providing these ancillary grid-support services either at residential or utility scale. However, the use of grid-forming inverters (GFMIs) is gaining momentum as the penetration-level of DERs increases and system inertia decreases. Under abnormal operating conditions, GFMIs tend to better preserve grid stability due to their intrinsic ability to balance loads without the aid of coordination controls. In order to gain and propose fundamental insights into the interfacing of GFMIs to real time simulation, this paper analyzes the dynamics of two different GFMI simulation models in terms of stability and load changes using a Power Hardware-in-the-Loop (PHIL) simulation testbed.
现代电网包括各种可再生分布式能源(DERs)作为一种策略,以遵守州和联邦机构实施的新的环境和可再生组合标准(RPSs)。通常,分布式电源包括使用电力电子(PE)接口与电网进行交互。最近,这种相互作用不仅集中在提供最大可用能量上,而且还集中在支持电网在异常条件下,如低电压/频率条件或非单位功率因数。在过去的几年中,电网跟随逆变器(gfli)在提供住宅或公用事业规模的辅助电网支持服务时已经证明了它们的价值。然而,随着DERs穿透水平的提高和系统惯性的减小,电网形成逆变器(GFMIs)的使用正在获得动力。在异常运行条件下,gfmi具有无需协调控制就能平衡负载的内在能力,能够更好地保持电网的稳定性。为了获得并提出GFMI与实时仿真接口的基本见解,本文使用电源硬件在环(PHIL)仿真试验台分析了两种不同GFMI仿真模型在稳定性和负载变化方面的动态。
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引用次数: 11
High efficiency 6-junction solar cells for the global and direct spectra 用于全局和直接光谱的高效6结太阳能电池
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198950
Ryan M. Francea, John F. Geisza, M. Steinera, K. Schultea, Iván Garcíab, Waldo Olavarriaa, M. Younga, Daniel J. Friedmana
We show 6-junction inverted metamorphic solar cells with high efficiencies under both the global and direct spectrum, and discuss improvements to device components. High voltage AlGaInP subcells are demonstrated on GaAs substrates miscut 2° towards (111)B by using Sb surfactant to reduce atomic ordering. This miscut enables high voltage and low dislocation density GaInAs subcells by using atomically-ordered GaInP-based graded buffers. One-sun efficiencies of 39.2 ± 1.3% under the global spectrum and 39.4 ± 1.1% direct spectrum have been demonstrated by using these high voltage subcell components. For high efficiency under the concentrated direct spectrum, low resistance is also necessary, which requires a challenging and nonintuitive optimization of tunnel junctions and heterobarriers. Increasing the thickness of a (Al)GaInAs spacer layer between the back surface fields (BSF) and tunnel junctions (TJ) of latticemismatched subcells reduces nonlinear resistance, which implies a detrimental interaction between the BSF and TJ. Concentrator devices with optimized spacer layers show reduced effective resistance and maintain fill factor ≫ 75% at 1100 suns. Device efficiencies under the concentrated direct spectrum peak at 47.1 ± 3.2% at 143 suns.
我们展示了在全局和直接光谱下都具有高效率的6结反向变质太阳能电池,并讨论了对器件组件的改进。利用Sb表面活性剂降低原子有序度,在GaAs衬底上向(111)B方向错切2°,展示了高压AlGaInP亚电池。这种错误切割通过使用基于原子有序gainp的梯度缓冲来实现高电压和低位错密度的GaInAs亚电池。使用这些高压亚电池组件,在全球光谱和直接光谱下的一次太阳效率分别为39.2±1.3%和39.4±1.1%。为了在集中的直接光谱下实现高效率,还需要低电阻,这就需要对隧道结和异质势垒进行具有挑战性和非直观的优化。增加栅格发射匹配亚电池的后表面场(BSF)和隧道结(TJ)之间的(Al)GaInAs间隔层的厚度可以降低非线性电阻,这意味着BSF和隧道结之间存在有害的相互作用。具有优化间隔层的聚光器件在1100个太阳下有效电阻降低,填充系数保持在75%。在143个太阳照射下,器件效率峰值为47.1±3.2%。
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引用次数: 3
Suggested Modifications for Bifacial Capacity Testing 对双面容量测试的建议修改
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198974
Martin Waters, C. Deline, J. Kemnitz, J. Webber
Capacity tests such as those described in ASTM 2848 and IEC 61724-2 are widely used during the contracting and acceptance testing of photovoltaic systems. With the increasing deployment of bifacial photovoltaic modules, there is a need to develop a standardized approach to capacity test these systems. Although variability and bias error were inherently higher for the measured capacity of bifacial systems, they could be reduced to a level consistent with the monofacial reference system by appropriate incorporation of rear irradiance—either measured or modeled. Three field installations provided bifacial system capacity that was measured with a mean bias error and standard deviation within 1% over the 2–10-month observation period. Capacity test accuracy could be improved further by using the measured back-of-module temperature and the IEC 61724-2 test method for well curated systems.
ASTM 2848和IEC 61724-2中描述的容量测试在光伏系统的签约和验收测试中被广泛使用。随着双面光伏组件部署的增加,有必要开发一种标准化的方法来测试这些系统的容量。虽然双面系统测量能力的可变性和偏置误差固有地更高,但通过适当地结合背面辐照度(测量或建模),它们可以降低到与单面参考系统一致的水平。三个现场装置提供了双面系统容量,在2 - 10个月的观察期内,平均偏置误差和标准偏差在1%以内。通过使用测量的模块后端温度和IEC 61724-2测试方法,可以进一步提高容量测试的精度。
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引用次数: 7
Microcrack Formation in Silicon Solar Cells during Cold Temperatures 低温下硅太阳能电池微裂纹的形成
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198968
H. Seigneur, E. Schneller, Jason Lincoln, Hossein Ebrahimi, Hossein Ebrahimi, A. Gabor, M. Rowell, Victor Victor Huayamave
A single brief exposure of a photovoltaic (PV) module or coupon to cold temperatures down to -40°C, the lower limit in IEC photovoltaic testing standards, significantly degrades the fracture strength of silicon solar cells. To understand the mechanism behind the fracture strength degradation, we built a finite element model of a single cell encapsulated coupon and reduced the temperature isothermally from 25°C to -40°C and from 150°C to -40°C. Our modeling results confirm that the regions next to the interconnect wires see high stresses. The silicon wafer bends around the top wire towards the glass; whereas, the entire coupon curves in the opposite direction. The first-principle stress in the entire silicon wafer was found to be compressive, mostly in plane in the direction perpendicular to the wires, yet unable to cause a failure due to the much larger compressive strength of silicon. On the other hand, out-of-plane shear stresses on each side of the ribbons were observed to exceed considerably the shear strength of silicon, most likely causing the formation of microcracks. These microcracks that form during cooling can later propagate into full cracks at relatively low front side loads that place the cells into tensile stress. We also investigated whether the silicon cell may be buckling due to high compressive stresses due to the backsheet and encapsulant shrinkage. Index Terms— Cooling, Failure analysis, Numerical models, Photovoltaic cells, Solar Panels, Surface cracks, Thermal analysis, Thermal expansion, Thermal stresses.
将光伏(PV)组件或组件短暂暴露在低至-40°C (IEC光伏测试标准的下限)的低温下,会显著降低硅太阳能电池的断裂强度。为了了解断裂强度下降背后的机制,我们建立了单个细胞封装接头的有限元模型,并将温度从25°C等温降低到-40°C,从150°C等温降低到-40°C。我们的建模结果证实,靠近互连线的区域看到高应力。硅晶片绕着顶端的金属丝向玻璃弯曲;而整个券息曲线的方向相反。发现整个硅片的第一原理应力是压应力,主要在垂直于导线方向的平面上,但由于硅的抗压强度大得多,因此无法导致失效。另一方面,观察到条带两侧的面外剪切应力大大超过硅的剪切强度,很可能导致微裂纹的形成。这些在冷却过程中形成的微裂纹随后会在相对较低的前侧载荷下扩展成完整的裂纹,从而使电池处于拉伸应力状态。我们还研究了硅电池是否可能由于背板和封装剂收缩引起的高压应力而屈曲。索引术语-冷却,失效分析,数值模型,光伏电池,太阳能电池板,表面裂纹,热分析,热膨胀,热应力。
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引用次数: 5
期刊
2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)
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