TG-FTIR Analysis on Sawdust Catalytic Pyrolysis with CaO

Q. Ma, Qinhui Wang, Long Han, Chun-jiang Yu, Zhong-yang Luo
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引用次数: 1

Abstract

Due to the global warming and energy crisis, the utilization of biomass in zero emission system has aroused more attention. In this study, the effect of catalyst CaO on sawdust pyrolysis was investigated using a thermogravimetric analyzer coupled with Fourier transform infrared analyzer (TG-FTIR). The thermogravimetric analysis showed that the characteristics of sawdust pyrolysis were affected by CaO addition, which presented two main stages of volatile releasing and increased residue yield. With increasing CaO addition, the weight loss in the first main stage decreased but that in the second stage increased, and the pyrolysis reaction moved to higher temperatures. With increasing heating rate, the weight loss in the first main stage decreased and the reaction shifted to lower temperatures.
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木屑与CaO催化热解的TG-FTIR分析
由于全球变暖和能源危机,生物质在零排放系统中的利用引起了越来越多的关注。采用热重分析仪和傅里叶变换红外分析仪(TG-FTIR)研究了催化剂CaO对木屑热解的影响。热重分析表明,CaO的加入影响了木屑的热解特性,呈现出挥发分释放和残渣产率提高两个主要阶段。随着CaO添加量的增加,第一主段失重量减小,第二主段失重量增大,热解反应温度升高。随着升温速率的增加,第一主段失重量减小,反应温度降低。
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