Application of Al2O3 film for stabilization of charge properties of the SiO2/p-Si interface

A. Kim, N. A. Serko, P. E. Khakuashev, A. N. Kolky, S. Yurchuk
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Abstract

The influence of aluminum oxide films obtained by high-frequency cathode sputtering of an Al2O3 target in argon atmosphere on charging properties of the SiO2/p-Si interface was investigated. High-frequency C-V characteristics for MIS-structure with one-layer dielectric films: SiO2 (0,10 µm and 0,36 µm), Al2O3 (0,14 µm) – and its double-layers compositions were measured. Experiment was carried out with a KDB-4.5 and a KDB-5000 substrates. Some electrophysical parameters of the obtained films such as UFB and Qss were calculated. Based on experimental results it was confirmed that the embedded negative charge of Al2O3 film prevented the formation of the inversive layer on p-Si surface by compensation of the embedded positive charge of SiO2 film and enhancement of semiconductor surface with majority charge carriers and, thus, allowed stabilization of charge properties of the SiO2/p-Si interface. The applicability of Al2O3 film as additional dielectric covering for manufacture technology of photodiodes on high-resistance p-Si was confirmed by applying on a multi-element p-i-n photosensitive element (PE) as an example. It was established that passivation of silicon dioxide on periphery and between the elements of PE by Al2O3 film improved I-V characteristics and insulation resistance, which lead to increased yield rate of photodiodes.
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Al2O3薄膜在稳定SiO2/p-Si界面电荷性能中的应用
研究了在氩气气氛中高频阴极溅射Al2O3靶材制备的氧化铝膜对SiO2/p-Si界面充电性能的影响。测量了具有单层介质膜SiO2(0,10µm和0,36µm)、Al2O3(0,14µm)及其双层成分的miss结构的高频C-V特性。实验采用KDB-4.5和KDB-5000衬底。计算了所得膜的UFB和Qss等电物理参数。实验结果表明,Al2O3薄膜内嵌的负电荷通过补偿SiO2薄膜内嵌的正电荷和增强半导体表面的大多数载流子,阻止了p-Si表面上逆层的形成,从而使SiO2/p-Si界面的电荷性质趋于稳定。以多元素p-i-n光敏元件(PE)为例,证实了Al2O3薄膜作为附加介质覆盖层在高阻p-Si光电二极管制造技术中的适用性。结果表明,Al2O3薄膜对PE外围和元件之间的二氧化硅进行钝化,改善了光电二极管的I-V特性和绝缘电阻,从而提高了光电二极管的成品率。
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