Induction melting of an Al-50Cu alloy for improved homogeneity required for powder spheroidisation

R. van der Merwe, H. Bissett, I. Van der Walt, L. Cornish
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Abstract

Copper alloys are typically produced by conventional casting processes, including spark plasma sintering (SPS), which often produce inhomogeneous mixtures of Cu or Al precipitates and unwanted intermetallic phases in solid products. Induction melting should provide good mixing, controlled heating and melt stirring, potentially improving homogeneity. Homogeneous melts should produce homogeneous powders, giving better properties in additive manufacturing (AM). To ascertain homogeneity, a density test was developed. After comminution, homogeneous powders can be used to produce high quality components. To manufacture dense AM components, spheroidised powders are needed because they increase particle packing and powder flow. An Al-50Cu (at.%) button was produced by high-frequency (HF) induction melting, to give better mixing and hence phase distributions. To identify the phases and their distributions, the as-cast sample was studied using scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD), as well as absolute density using helium pycnometry. Results indicated inhomogeneity in the samples, due to Al loss, complex solidification and the densest phase settling at the bottom of the button.
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感应熔炼Al-50Cu合金以改善粉末球化所需的均匀性
铜合金通常是通过传统的铸造工艺生产的,包括火花等离子烧结(SPS),这通常会在固体产品中产生不均匀的Cu或Al沉淀和不需要的金属间相混合物。感应熔炼应提供良好的混合,控制加热和熔体搅拌,潜在地改善均匀性。均质熔体应该产生均匀的粉末,在增材制造(AM)中提供更好的性能。为了确定均匀性,开发了密度测试。粉碎后,均质粉末可用于生产高质量的组件。为了制造致密的增材制造组件,需要球化粉末,因为它们增加了颗粒堆积和粉末流动。采用高频(HF)感应熔炼法制备了Al-50Cu (at.%)钮扣,得到了较好的混合和相分布。利用扫描电子显微镜(SEM)、x射线能谱(EDX)和x射线衍射仪(XRD)对铸态样品进行了相及其分布的研究,并用氦比重仪对铸态样品的绝对密度进行了研究。结果表明,由于Al的损失、复杂的凝固和钮扣底部最致密的相沉降,样品中存在不均匀性。
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