Attempt to Design a Facile Lead-free Halide Double Perovskite Cs2AgBiBr6 p-i-n Solar Cell

J. Jang, Jinyoung Kim
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Abstract

Recently the power conversion efficiency of lead (Pb)-based organometallic halide perovskite materials was reached to 23 %. Despite of its excellent performance, the issue of environment and health still remained due to the lead toxicity. Therefore, the double perovskite (A2B'B"X6) which was composed of binary B site cations was particularly investigated as suitable non-toxic and lead-free perovskite composition. In this work, we synthesized all inorganic halide double perovskite composition, Cs2AgBiBr6 with dropping method. Furthermore, the p-i-n double perovskite solar cell was designed and improved by applying various hole and electron transporting layers based on the optimization of band alignment.
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设计一种简易无铅卤化物双钙钛矿Cs2AgBiBr6 p-i-n太阳能电池的尝试
近年来,铅基有机金属卤化物钙钛矿材料的功率转换效率达到23%。尽管其性能优异,但由于铅的毒性,环境和健康问题仍然存在。因此,特别研究了由二元B位阳离子组成的双钙钛矿(A2B’B’X6)作为合适的无毒无铅钙钛矿组合物。本文采用滴法合成了全无机卤化物双钙钛矿组合物Cs2AgBiBr6。在优化带向的基础上,设计并改进了p-i-n双钙钛矿太阳能电池。
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