The chemical fixation of carbon dioxide by tetramethylguanidine and triazabicyclo dec-5-ene bases

M. S. Batagarawa, F. Adam
{"title":"The chemical fixation of carbon dioxide by tetramethylguanidine and triazabicyclo dec-5-ene bases","authors":"M. S. Batagarawa, F. Adam","doi":"10.4314/CSJ.V7I1.4","DOIUrl":null,"url":null,"abstract":"The fixation of CO 2 using guanidine bases; 1,1,3,3-tetramethylguanidine (TMG) and 5,7-triazabicyclo[4.4.0] dec-5-ene (TBD) has been investigated. Solution Nuclear magnetic resonance (NMR) studies were carried out for the reaction between CO 2 and the guanidine bases at normal temperature and pressure, i.e Ca. 30 °C and 1 atm. Analysis of results obtained using 1- dimentional 13 C NMR and 2-dimentional 15 N (HMBC) both indicated successful reaction between CO 2 and TBD and also CO 2 with TMG. Both products were observed to be stable at room temperature and pressure. Based on the results obtained, it was concluded that, the CO 2 can be fixed with TMG and TBD at normal conditions of temperature and pressure. Finally it was also proposed that, the method used could be useful for the uptake and release of atmospheric CO 2 . Keywords: Carbon dioxide, Chemical fixation, Heteronuclear Multiple-Bond Correlation Tetramethylguanidine, Triazabicyclo decene","PeriodicalId":9900,"journal":{"name":"ChemSearch Journal","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemSearch Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4314/CSJ.V7I1.4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The fixation of CO 2 using guanidine bases; 1,1,3,3-tetramethylguanidine (TMG) and 5,7-triazabicyclo[4.4.0] dec-5-ene (TBD) has been investigated. Solution Nuclear magnetic resonance (NMR) studies were carried out for the reaction between CO 2 and the guanidine bases at normal temperature and pressure, i.e Ca. 30 °C and 1 atm. Analysis of results obtained using 1- dimentional 13 C NMR and 2-dimentional 15 N (HMBC) both indicated successful reaction between CO 2 and TBD and also CO 2 with TMG. Both products were observed to be stable at room temperature and pressure. Based on the results obtained, it was concluded that, the CO 2 can be fixed with TMG and TBD at normal conditions of temperature and pressure. Finally it was also proposed that, the method used could be useful for the uptake and release of atmospheric CO 2 . Keywords: Carbon dioxide, Chemical fixation, Heteronuclear Multiple-Bond Correlation Tetramethylguanidine, Triazabicyclo decene
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
四甲基胍和三氮杂环十二-5-烯碱对二氧化碳的化学固定作用
胍基对co2的固定作用研究了1,1,3,3-四甲基胍(TMG)和5,7-三氮杂环[4.4.0]十二-5-烯(TBD)。在常温常压下,即30°C和1atm下,对CO 2与胍基之间的反应进行核磁共振(NMR)研究。利用一维13c NMR和二维15n (HMBC)分析结果均表明co2与TBD和co2与TMG反应成功。两种产物在常温常压下均稳定。结果表明,在常温常压条件下,TMG和TBD可以固定co2。最后还提出,该方法可用于研究大气co2的吸收和释放。关键词:二氧化碳,化学固定,杂核多键相关四甲基胍,三氮杂环癸烯
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Mangifera indica leaves powder for the removal of rhodamine B.: isotherm and kinetic studies Evaluation of heavy metals contamination in some irrigated vegetables from Kano, Nigeria Liquid-assisted Mechanochemical Conversion of 2-hydroxy-3- methoxybenzaldehyde and Some Primary Aromatic Amines to Corresponding Schiff bases Solid State Synthesis, Spectroscopic and X-ray Studies of Cu(II) Schiff base Complex Derived from 2-Hydroxy-3-methoxybenzaldehyde and 1,3- Phenylenediamine Trimethylamine N-oxide promoted decarbonylation reactions of molybdenum and tungsten hexacarbonyls with dimethylglyoxime
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1