Determination of ion-exchanged Co2+ cation in Co-ZSM-5 by temperature-programmed desorption

Chul Wee Lee , Paul Joe Chong , Young Chul Lee , Chong Shik Chin , Larry Kevan
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引用次数: 8

Abstract

It is shown that temperature-programmed desorption of adsorbed NO on Co-ZSM-5 zeolite used in selective catalytic reduction can accurately measure the amount of Co2+ cation for Co/Al ratios from 0 to 0.42 where the 0.42 limit corresponds to 84% maximum exchange. Evidence is also shown for the formation of cobalt oxide particles in Co-ZSM-5 for Co/Al ratios above 0.42.

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程序升温解吸法测定Co-ZSM-5中离子交换的Co2+阳离子
结果表明,在Co/Al比值为0 ~ 0.42的条件下,Co- zsm -5分子筛对吸附的NO进行程序升温解吸,可准确测定Co/Al比值为0.42的Co2+阳离子量,其中0.42极限对应84%的最大交换。在Co/Al比高于0.42时,Co- zsm -5中还会形成氧化钴颗粒。
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Author index Subject index Contents Investigation of organosilanes as structure-directing agents in zeolite synthesis The influence of gel properties on the kinetics of crystallization and particulate properties of MFI-type zeolities. I. The influence of time and temperature of gel ageing on the particulate properties of silicalite-1 microcrystals
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