Use of Mg-Al/hydrotalcite Catalyst in Biodiesel Production from Avocado Seed Oils: A Preliminary Study

Irvan Maulana Firdaus, Tri Fitriany, M. N. Hidayah, A. Soleh, Khilman Husna Pratama, F. Febiyanto
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引用次数: 5

Abstract

Biodiesel production of avocado seed oils has been carried out using the heterogeneous catalyst of Mg-Al/hydrotalcite. Transesterification process was conducted by varying temperature reaction and oil-methanol molar ratio. The reaction temperature was 30, 40, 50, and 60°C, whereas the oil-methanol molar ratio was 1:3, 1:6, 1:9, and 1:12, respectively. As-synthesized Mg-Al/hydrotalcite catalyst was characterized using X-ray diffraction and FTIR. Meanwhile, the biodiesel was analyzed their density, viscosity, water content and 1H-NMR analysis. The results showed that optimum condition in biodiesel production was oil-methanol molar ratio of 1:6 at a reaction temperature of 60°C for 60 minutes and catalyst quantity of 2% yielding biodiesel conversion percentage was approximately 15.90%. However, this preliminary findings showed that Mg-Al/hydrotalcite was able to convert the avocado seed oils into biodiesel even if still need further analysis and research so that produces a higher percentage of biodiesel conversion.
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Mg-Al/水滑石催化剂在鳄梨籽油制备生物柴油中的应用初步研究
采用Mg-Al/水滑石异相催化剂对牛油果籽油进行了生物柴油的制备。通过变温度反应和油-甲醇摩尔比进行酯交换反应。反应温度为30、40、50和60℃,油-甲醇摩尔比分别为1:3、1:6、1:9和1:12。用x射线衍射和红外光谱对合成的镁铝/水滑石催化剂进行了表征。同时对生物柴油进行了密度、粘度、含水量分析和1H-NMR分析。结果表明,制备生物柴油的最佳条件是油-甲醇摩尔比为1:6,反应温度为60℃,催化剂用量为2%,反应时间为60分钟,生物柴油的转化率约为15.90%。然而,这一初步研究结果表明,Mg-Al/水滑石能够将鳄梨籽油转化为生物柴油,即使还需要进一步的分析和研究,以产生更高比例的生物柴油转化率。
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