REMOVAL OF DIVALENT CADMIUM IONS FROM AQUEOUS SOLUTION USING LANTANA CAMARA LEAVES BIOCARBON

S. Shyla, R. M. Kumar, M. Singanan
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Abstract

The objective of this study is to investigate the removal of divalent cadmium ions from an aqueous solution using Lantana camara leaves biocarbon (LCBC). Batch experiments are conducted to test the effects of various parameters such as pH, initial metal ion concentration, amount of biocarbon, and contact time on the cadmium removal process at room temperature, which allows establishing as the optimum conditions a pH value of 4.0 and 2.5g/100 mL of biocarbon dose at the equilibrium time of 180 min. The maximum percentage removal of cadmium is 93.30%. Langmuir and Freundlich adsorption isotherms are used to verify the adsorption parameters, and the experimental data is well fitted to the Langmuir model. Analysis of the biosorption kinetics shows that the pseudo-second-order model is well fitted for Cd (II) ions removal. The correlation coefficient (r2) for the second-order model is 0.9848. The results reveal LCBC as an efficient, low cost, and harmless to environment adsorbent for the removal of Cd (II) ions in the biosorption process.
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利用大灯笼叶生物碳去除水溶液中的二价镉离子
本研究的目的是研究用大灯笼叶生物碳(LCBC)去除水溶液中的二价镉离子。通过批量实验,考察了pH、初始金属离子浓度、生物炭用量、接触时间等参数对常温下脱镉过程的影响,确定了pH为4.0、2.5g/100 mL生物炭用量为最佳条件,平衡时间为180 min,镉的最大去除率为93.30%。采用Langmuir吸附等温线和Freundlich吸附等温线对吸附参数进行了验证,实验数据与Langmuir模型拟合良好。生物吸附动力学分析表明,拟二级吸附模型对Cd (II)离子的去除效果较好。二阶模型的相关系数r2为0.9848。结果表明,LCBC是一种高效、低成本、对环境无害的生物吸附Cd (II)离子吸附剂。
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