Simple and Rapid Device for Mercury Detection Based on The Formation of Mercury(II)-Dithizonate on Polytetrafluoroethylene (PTFE) Membrane

Hermin Sulistyarti, Mega Madha Wijaya, Dewi Setyowati, S. Sutrisno, Erwin Sulistyo
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引用次数: 1

Abstract

A new analytical device for mercury detection has been developed by doping dithizone on to hydrophobic PTFE (polytetrafluoroethylene) membrane to form a blue dithizone membrane which instantaneously changed to orange color of mercury(II)-dithizonate complex, when this dithizone membrane was contacted to mercury(II) solution. The higher concentration of mercury showed the greater intensity of the orange colour mercury(II)-dithizonate complex. The design and chemicals were optimized to obtain the best performance for mercury measurement. This method is prospective as mercury test kit for simple, low cost, and rapid semi-quantitative method for mercury(II) determination from 1-10 mgL-1 suits for on-site mercury detection and has been applied to cosmetics with satisfactory results.
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基于聚四氟乙烯(PTFE)膜上汞(II)-二硫代酸盐形成的简单快速汞检测装置
将双硫腙掺杂到疏水性聚四氟乙烯(PTFE)膜上,形成蓝色的双硫腙膜,当双硫腙膜与汞(II)溶液接触时,双硫腙膜立即变成橙色的汞(II)-二硫腙配合物。汞浓度越高,呈现的橙色汞(II)-二硫代酸盐络合物的强度越大。为了获得最佳的汞测量性能,对设计和化学物质进行了优化。该方法是一种简单、低成本、快速的1 ~ 10 mg / l汞(II)半定量检测试剂盒,适用于现场汞检测,并已应用于化妆品中,结果满意。
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