Self-Assembled Soft Nanomaterials from Renewable Resources

G. John
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引用次数: 1

Abstract

A set of amphiphilic glycolipids were synthesized from cardanol (a by-product of cashew industry) and diaminopyridine (DAP). These amphiphiles encompass selfassembling units such as long hydrophobic saturated or unsaturated chain, open or closed sugar as headgroup and aromatic (phenyl or DAP) as linker. Amphiphiles from both series (cardanyl and DAP) exhibited excellent self-assembling properties to produce various lipid based materials ranging from structurally unordered fibers to highly uniform nanotubes. Their self-assembling properties were investigated by various techniques including EF-TEM, SEM, XRD and DSC. The nanotubes are comprised of bilayer structure with interdigitated alkyl chains associated through hydrophobic
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可再生资源自组装软纳米材料
以腰果工业副产物腰果酚和二氨基吡啶(DAP)为原料合成了一组两亲性糖脂。这些两亲体包括自组装单元,如长疏水饱和或不饱和链,开或闭糖作为头基,芳香(苯基或DAP)作为连接剂。这两个系列的两亲分子(红桃基和DAP)都表现出优异的自组装性能,可以生产各种脂基材料,从结构无序的纤维到高度均匀的纳米管。采用透射电镜、扫描电镜、x射线衍射和DSC等技术对其自组装性能进行了研究。纳米管由双分子层结构组成,并通过疏水性相互连接
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