Comparison of Spectral Characteristics of TiO2@Ag and Ag@TiO2 Core-Shell Nanoparticles

T. Bulavinets, I. Yaremchuk, V. Fitio, A. Barylyak, Y. Bobitski
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引用次数: 2

Abstract

Comparison of spectral characteristics of TiO2@Ag and Ag@TiO2 core-shell nanoparticles has been carried out. It is shown that in the case of TiO2@Ag the spectral position of the extinction peaks shifts to the long-wave spectrum region when the shell thickness changes and when the nanostructure is deformed (elongated). Ag@TiO2 is characterized by appearance of the additional plasmonic peak. This main peak shifts to the short-wave spectrum region when the shell thickness increases and under deformation. Moreover, the additional peak is practically not sensitive to such changes. It should be noted that with a certain shell thickness such structure will have characteristics similar to silver nanoparticles.
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TiO2@Ag和Ag@TiO2核壳纳米粒子光谱特性的比较
对TiO2@Ag和Ag@TiO2核壳纳米粒子的光谱特性进行了比较。结果表明,在TiO2@Ag的情况下,随着壳层厚度的变化和纳米结构的变形(拉长),消光峰的光谱位置向长波光谱区偏移。Ag@TiO2以附加等离子体峰的出现为特征。当壳体厚度增大和变形时,主峰向短波频谱区偏移。此外,附加峰实际上对这种变化不敏感。值得注意的是,在一定的壳厚度下,这种结构将具有类似于银纳米粒子的特性。
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