{"title":"Kinetics and Mechanism of Oxidation of L-Ascorbic Acid by Pt(IV)(aq) in Aqueous Hydrochloric Acid Medium","authors":"S. Senapati, S. Das, A. Patnaik","doi":"10.1155/2012/143734","DOIUrl":null,"url":null,"abstract":"Reduction of [PtCl6]2− by L-ascorbic acid (H2ASc) in 0.1 M aqueous acid medium has been investigated spectrophotometrically under pseudo-first order condition at [PtCl6]2− = 0.005–0.007 mol dm−3, 0.05 ≤ [H2ASc]/mol dm−3 ≤ 0.3, 298 K ≤ ≤ 308 K, [H","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2012-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Physical Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/2012/143734","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
Reduction of [PtCl6]2− by L-ascorbic acid (H2ASc) in 0.1 M aqueous acid medium has been investigated spectrophotometrically under pseudo-first order condition at [PtCl6]2− = 0.005–0.007 mol dm−3, 0.05 ≤ [H2ASc]/mol dm−3 ≤ 0.3, 298 K ≤ ≤ 308 K, [H
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