Люминесцентные свойства индивидуальных центров "кремний-вакансия" в CVD-наноалмазах, выращенных на различных подложках

Д.Г. Пастернак, Д. А. Калашников, В Леонг, К. Чиа, А.М. Ромшин, С. В. Кузнецов, А. К. Мартьянов, В. С. Седов, Л.А. Кривицкий, И. И. Власов
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Abstract

The application of the technique of resonant excitation of photoluminescence at low temperatures using a narrow-band tunable laser significantly expands the possibilities of spectral investigation of individual luminescent centers in nanodiamonds, even in conditions of high concentrations of such centers. In this paper, a comparative analysis of the spectral characteristics of individual Silicon-Vacancy (SiV) centers in nanodiamonds grown with a spontaneous nucleation technique on germanium and silicon substrates is carried out. Studied diamond nanoparticles have a characteristic size of 300 nm and contain large ensembles of SiV centers. It was found that during the transition from silicon substrates, which are traditionally used in the CVD synthesis of diamonds, to germanium substrates, the spectral characteristics of the photoluminescence of SiV centers almost do not change.
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在不同底座上生长的CVD-纳米钻石中,硅-空位中心的发光特性
利用窄带可调谐激光在低温下共振激发光致发光技术的应用,大大扩展了纳米金刚石中单个发光中心的光谱研究的可能性,即使在这种中心高浓度的条件下也是如此。本文对自发成核技术在锗和硅衬底上生长的纳米金刚石中单个硅空位(SiV)中心的光谱特征进行了比较分析。所研究的金刚石纳米颗粒的特征尺寸为300 nm,并且含有大量的SiV中心。研究发现,从传统上用于CVD合成金刚石的硅衬底到锗衬底的转变过程中,SiV中心的光致发光光谱特性几乎没有变化。
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