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Релятивистские расчеты энергий низко возбужденных состояний 1sns, 1snp, 1snd и вероятностей однофотонных переходов 1snl -> 1sn'l' в гелиеподобном ионе урана 低激发性状态1sns、1snp、1snd和氦型铀单光子跃迁概率相对论计算
Pub Date : 2023-02-28 DOI: 10.21883/OS.2023.03.55379.4569-22
N. Dulaev, M. Y. Kaygorodov, A. Malyshev, I. Tupitsyn, V. Shabaev
For heliumlike uranium, the energies of the singly-excited 1sns, 1snp, and 1snd states with n ≤ 4 and the probabilities of the one-photon 1s3d -> 1s2p, 1s3p -> 1s2s, 1s3p -> 1s2p and 1s4d -> 1s2p transitions are evaluated. The calculations are performed within the Breit approximation using the configuration-interaction method in the basis of the Dirac-Fock-Sturm orbitals. The QED corrections to the energy levels are calculated employing the model-QED-operator approach. The nuclear recoil, frequency-dependent Breit-interaction, nuclear polarization, and nuclear deformation corrections are taken into account as well.
对于类氦铀,计算了n≤4的单激发1sns、1snp和1snd态的能量,以及单光子1s3p -> 1s2p、1s3p -> 1s2s、1s3p -> 1s2p和1s4d -> 1s2p跃迁的概率。在Dirac-Fock-Sturm轨道的基础上,使用构型相互作用方法在Breit近似内进行了计算。采用模型-QED算子的方法计算了QED对能级的修正。同时考虑了核反冲、频率相关的布雷特相互作用、核极化和核变形修正。
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引用次数: 0
Определение концентрации электронов проводимости в монокриcталлических образцах n-GaSb по спектрам отражения в дальней инфракрасной области при T=295 K 在T=295 K下,n-GaSb远红外反射光谱测定导电性电子浓度
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56126.4318-23
А. Г. Белов, Е. В. Молодцова, С.С. Кормилицина, Р. И. Козлов, Е.О. Журавлев, Степан Андреевич Климин, Надежда Николаевна Новикова, В. А. Яковлев
A method is proposed for separately determining the concentrations of "light" and "heavy" electrons in n-GaSb. It is based on the analysis of reflection spectra in the far infrared region, taking into account the plasmon-phonon coupling. Calibration curves have been calculated that allow one to determine the concentrations of "light" and "heavy" electrons in GaSb using the frequency of high-energy coupled plasmon-phonon mode. For a series of n-GaSb samples the reflection spectra were measured and the concentrations of "light" and "heavy" electrons were determined at room temperature. Electrophysical Van der Paw measurements have been performed on the same samples at room temperature. By comparing the optical and Hall data, the ratios of the mobilities of "light" and "heavy" electrons (parameter b) were determined. This method of determining the value of the parameter b is used for the first time.
提出了一种分别测定n-GaSb中“轻”电子和“重”电子浓度的方法。它基于对远红外区域反射光谱的分析,考虑了等离子体-声子耦合。通过计算校准曲线,可以利用高能等离子体-声子耦合模式的频率确定GaSb中“轻”电子和“重”电子的浓度。测量了一系列n-GaSb样品在室温下的反射光谱,并测定了“轻”电子和“重”电子的浓度。在室温下对相同的样品进行了电物理范德柏测量。通过比较光学和霍尔数据,确定了“轻”电子和“重”电子的迁移率(参数b)。这种确定参数b值的方法是第一次使用。
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引用次数: 0
Спектроскопия спиновых флуктуаций редкоземельных ионов в кристаллах 晶体中稀土离子自旋波动光谱学
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55545.64-22
Валерий Сергеевич Запасский
Spin fluctuation spectroscopy (SNS) is a conceptually new version of magnetic resonance spectroscopy, experimentally demonstrated in 1981 and strongly developed in the last two decades. Atomic systems and semiconductors served as main objects of the SNS. It became possible to apply SNS to crystals with rare-earth impurities - classical objects of EPR spectroscopy and the subject of constant interest of P.P. Feofilov, only in recent years, due to specific combination of spectroscopic properties of rare-earth ions with characteristics of the stochastic signal formation in SNS. In this article, we consider the specific characteristics of application of SNS to crystals with rare-earth ions and briefly describe the results of experimental studies, which made it possible to significantly expand the scope of possibilities of this method.
自旋涨落光谱学是磁共振光谱学的一个新概念,在1981年得到实验证明,近20年来得到了大力发展。原子系统和半导体是SNS的主要对象。由于稀土离子的光谱特性与SNS中随机信号形成的特性的特殊结合,将SNS应用于含有稀土杂质的晶体——EPR光谱的经典对象,也是P.P. Feofilov一直感兴趣的课题,直到最近几年才成为可能。在本文中,我们考虑了SNS应用于稀土离子晶体的具体特点,并简要描述了实验研究的结果,这使得该方法的可能性范围得到了显著的扩展。
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引用次数: 0
Спектры оптических гармоник 2 и 3/2 при субрелятивистской лазерно-плазменной генерации рентгеновского излучения 光谐波谱2和3/2与亚伯拉底激光等离子体x射线产生有关
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.02.55003.19-23
М В Чащин, П. А. Щеглов, А.А. Таусенев, Михаил Михайлович Назаров, В.М. Гордиенко
The dependence of the visible spectrum (harmonics 2 and 3/2) and the output of Cu K-alpha X-ray radiation on the energy and duration of subrelativistic intensity femtosecond laser pulse acting on a copper foil is investigated. It was found that for secondary radiation, the determining factor is the energy density, and not the intensity and duration of the pulse. The power-law dependencies of the secondary output radiation on the duration and the pulse energy have a significantly different indicator. The tendencies of changing the shape of the spectrum for regions dominated by various mechanisms of plasma heating are revealed.
研究了作用在铜箔上的亚相对论性强飞秒激光脉冲的能量和持续时间对可见光谱(2次谐波和3/2次谐波)和Cu k - α x射线输出的影响。研究发现,二次辐射的决定因素是能量密度,而不是脉冲的强度和持续时间。二次输出辐射对持续时间和脉冲能量的幂律依赖性有明显不同的指标。揭示了各种等离子体加热机制主导区域光谱形状变化的趋势。
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引用次数: 0
Экситоны с переносом заряда в ВТСП купратах и никелатах 电荷转移到cprt和镍的轴突
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55553.70-22
А. С. Москвин
An analysis of the optical properties of compounds based on 3d elements provides valuable information about the electronic structure of the ground state and low-energy excitations. Thus, we show that the analysis of charge-transfer d-d excitons in the dielectric antiferromagnetic phase of cuprates and metastable low-energy electron-hole EH dimers being a result of their evolution after electron-lattice relaxation, turns out to be very fruitful not only for describing linear and nonlinear optical properties and photoinduced effects, but also to develop a promising model of charge triplets to describe the low-energy electronic structure and T-x phase diagrams of active CuO2 planes in cuprates of the T-La2CuO4 or T’-Nd2CuO4 type, as well as NiO2 planes in nickelates of the RNiO2 type, and their evolution with changes in the main energy parameters.
基于三维元素的化合物光学性质分析提供了有关基态和低能激发的电子结构的宝贵信息。因此,我们表明,分析铜酸盐的介电反铁磁相中的电荷转移d-d激子和亚稳低能电子-空穴EH二聚体(它们是电子-晶格弛豫后演化的结果)不仅对描述线性和非线性光学性质和光致效应非常有效,同时建立一个有前景的电荷三重体模型来描述T- la2cuo4或T ' -Nd2CuO4型铜酸盐中活性CuO2平面的低能电子结构和T-x相图,以及RNiO2型镍酸盐中的NiO2平面,以及它们随主要能量参数变化的演变。
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引用次数: 0
Теоретическое исследование магнитно-резонансных спектров псевдоперовскитных фрустрированных манганитов 假佩罗托酸性果蝠核磁共振光谱的理论研究
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.04.55554.57-22
Л. Э. Гончарь
The magnetic resonance spectra of frustrated manganite compounds La1/3Ca2/3MnO3 and BiMnO3 are calculated within the framework of orbitally dependent magnetic interactions model. The aim of the paper is an investigation of orbital structure influence and superexchange interactions’ competition effects on ferromagnetic or antiferromagnetic resonance spectra of these compounds. The description of the features of the resonance lower branches’ dependencies on the magnitude and direction of the magnetic field is proposed. It is shown that the main influence on the symmetry of dependencies is exerted by single-ion anisotropy of the Mn3+ ion, associated not only with the orbital structure, but also with the tilting distortions of oxygen octahedrons around the ions
在轨道依赖磁相互作用模型的框架内计算了受挫锰矿化合物La1/3Ca2/3MnO3和BiMnO3的磁共振波谱。本文的目的是研究轨道结构的影响和超交换相互作用对这些化合物的铁磁或反铁磁共振谱的竞争效应。提出了谐振下支路随磁场大小和方向变化的特征描述。结果表明,Mn3+离子的单离子各向异性不仅与轨道结构有关,还与离子周围氧八面体的倾斜畸变有关
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引用次数: 0
Трансформации спектров фотолюминесценции наноразмерных апконвертирующих фосфоров фантомами биологических тканей 生物组织纳米近变磷酸盐光照发光谱变换
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.06.55912.124-23
Е.М. Трифанова, Марина Юрьевна Николаева, А. П. Свиридов, Владимир Карпович Попов
Phantoms are often used to imitate biological tissues in laboratory conditions. Phantoms are usually made on the basis of natural and synthetic materials, as well as hydrogels and various bioactive compositions. Today to visualize biological tissues and study the processes occurring to them in in vitro and in vivo researches in real time, upconversion nanophosphors (UCNPs) are actively used. They have a whole set of unique photoluminescent properties and are promising components of modern tools for non-invasive optical diagnostics of the human and animals body. We have carried out the synthesis and complex characterization of β-NaYF4:Yb3+:Er3+/NaYF4 nanoparticles, which effectively convert radiation from the near-IR range into the visible region of the spectrum. The process has been developed to encapsulate them into the structure of aliphatic polyesters and to form bioresorbable polylactoglycolide scaffolds by anti-solvent 3D printing. We formed two types of tissue phantoms based on agarose, ultra-pasteurized cow's milk and melanin. Characterization and analysis of their optical properties were carried out. We studied the transformations of the photoluminescence spectrum of the synthesized UCNPs during the passage of their radiation through these phantoms, and performed the visualization of the photoluminescent polyester matrices placed in them.
在实验室条件下,幻影经常被用来模拟生物组织。幻影通常由天然和合成材料,以及水凝胶和各种生物活性成分制成。目前,上转换纳米荧光粉(UCNPs)被广泛应用于生物组织的实时可视化和体内外研究。它们具有一整套独特的光致发光特性,是人类和动物身体非侵入性光学诊断的现代工具的有前途的组成部分。我们进行了β-NaYF4:Yb3+:Er3+/NaYF4纳米颗粒的合成和复杂表征,该纳米颗粒有效地将近红外范围的辐射转换为光谱的可见区域。该工艺已被开发成将它们封装到脂肪族聚酯的结构中,并通过抗溶剂3D打印形成生物可吸收的聚乳酸支架。我们用琼脂糖、超巴氏杀菌牛奶和黑色素制作了两种组织模型。对它们的光学性质进行了表征和分析。我们研究了合成的UCNPs在其辐射通过这些幻影时的光致发光光谱的转换,并对放置在其中的光致发光聚酯矩阵进行了可视化。
{"title":"Трансформации спектров фотолюминесценции наноразмерных апконвертирующих фосфоров фантомами биологических тканей","authors":"Е.М. Трифанова, Марина Юрьевна Николаева, А. П. Свиридов, Владимир Карпович Попов","doi":"10.21883/os.2023.06.55912.124-23","DOIUrl":"https://doi.org/10.21883/os.2023.06.55912.124-23","url":null,"abstract":"Phantoms are often used to imitate biological tissues in laboratory conditions. Phantoms are usually made on the basis of natural and synthetic materials, as well as hydrogels and various bioactive compositions. Today to visualize biological tissues and study the processes occurring to them in in vitro and in vivo researches in real time, upconversion nanophosphors (UCNPs) are actively used. They have a whole set of unique photoluminescent properties and are promising components of modern tools for non-invasive optical diagnostics of the human and animals body. We have carried out the synthesis and complex characterization of β-NaYF4:Yb3+:Er3+/NaYF4 nanoparticles, which effectively convert radiation from the near-IR range into the visible region of the spectrum. The process has been developed to encapsulate them into the structure of aliphatic polyesters and to form bioresorbable polylactoglycolide scaffolds by anti-solvent 3D printing. We formed two types of tissue phantoms based on agarose, ultra-pasteurized cow's milk and melanin. Characterization and analysis of their optical properties were carried out. We studied the transformations of the photoluminescence spectrum of the synthesized UCNPs during the passage of their radiation through these phantoms, and performed the visualization of the photoluminescent polyester matrices placed in them.","PeriodicalId":24059,"journal":{"name":"Оптика и спектроскопия","volume":"27 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85440673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ап-конверсионная люминесценция твердых растворов CaF-=SUB=-2-=/SUB=--SrF-=SUB=-2-=/SUB=--HoF-=SUB=-3-=/SUB=- при возбуждении на уровень -=SUP=-5-=/SUP=-I-=SUB=-7-=/SUB=- ионов Ho-=SUP=-3+-=/SUP=- CaF- 2-= -2-= - SUB -2-= -2-= -2-= -3-= - SUB -3-= -3-= -3-= - SUP=- 7- SUP=- 7
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.03.55384.4085-22
М.К. Бубнов, С.А. Букарев, Сергей Викторович Гущин, Василий Андреевич Конюшкин, Сергей Валентинович Кузнецов, Александр Александрович Ляпин, A.H. Накладов, П. А. Рябочкина, В. В. Воронов, П. П. Федоров
Up-conversion luminescence spectra of CaF2-SrF2-HoF3 single crystals were investigated upon excitation by laser radiation with a wavelength of 1940 nm to the 5I7 level of Ho3+ ions. The CaF2-SrF2-HoF3 single crystals were grown by the vertical directional crystallization method. For these excitation conditions, quantitative characteristics of the up-conversion luminescence of Ho3+ ions were determined: energy yield, chromaticity coordinates, and correlated color temperatures. The possibility of increasing the efficiency of solar cells due to the conversion of infrared radiation in CaF2-SrF2-HoF3 crystals was considered.
用波长为1940 nm的激光激发至5I7能级的Ho3+离子,研究了CaF2-SrF2-HoF3单晶的上转换发光光谱。采用垂直定向结晶法生长CaF2-SrF2-HoF3单晶。在这些激发条件下,确定了Ho3+离子上转换发光的定量特征:能产率、色度坐标和相关色温。考虑了利用红外辐射在CaF2-SrF2-HoF3晶体中的转换来提高太阳能电池效率的可能性。
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引用次数: 0
Сочетание полого сапфирового волновода и иммерсионной линзы для ТГц эндоскопии сверхвысокого разрешения 超高分辨率中空蓝宝石波导与浸润透镜结合
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.06.55925.123-23
А. С. Кучерявенко, В.А. Желнов, Н.В. Черномырдин, В. Н. Курлов, К. И. Зайцев, Г.М. Катыба
The development of terahertz (THz) imaging methods is hampered by the low spatial resolution of traditional diffraction-limited imaging systems, mainly due to the large wavelength of used radiation (from a few of mm to tens of µm). To solve this problem, we have proposed a new method of THz endoscopy with subwavelength spatial resolution, which is designed to study hard-to-reach areas of living organisms in vivo. A hollow-core sapphire tube with polytetrafluoroethylene outer coating is used as a waveguide, in which the antiresonant principle of radiation transmission is implemented. The waveguide and the immersion lens are optimized to provide high optical characteristics in a given wavelength range to ensure the best focusing. Two immersion lenses made of sapphire and silicon were developed and fabricated, which were then mounted on plane-parallel windows fixed on the rear end of the waveguide. The study of the field intensity distribution on the shadow side of the “waveguide–lens” system revealed a focal spot diameter of ≃0.2λ in the case of a lens made of sapphire and ≃0.3λ in the case of a lens made of crystal silicon at a wavelength λ = 500 µm, which significantly exceeds the Abbe diffraction limit. This agrees with our numerical predictions and demonstrates the promise of using the proposed endoscope for measurements with subwavelength resolution.
太赫兹(THz)成像方法的发展受到传统衍射受限成像系统低空间分辨率的阻碍,主要是由于使用的辐射波长大(从几毫米到几十微米)。为了解决这一问题,我们提出了一种具有亚波长空间分辨率的太赫兹内窥镜新方法,该方法旨在研究生物体内难以到达的区域。采用外涂聚四氟乙烯的空心蓝宝石管作为波导,实现了辐射传输的抗谐振原理。波导和浸没透镜经过优化,在给定波长范围内提供高光学特性,以确保最佳聚焦。研制并制造了两个由蓝宝石和硅制成的浸没透镜,然后将其安装在固定在波导后端的平面平行窗口上。对“波导-透镜”系统阴影侧场强分布的研究表明,在波长λ = 500µm处,蓝宝石透镜的焦点光斑直径为0.2λ,晶体硅透镜的焦点光斑直径为0.3λ,明显超过了Abbe衍射极限。这与我们的数值预测一致,并证明了使用所提出的内窥镜进行亚波长分辨率测量的前景。
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引用次数: 0
Датчик угла поворота на основе одномерного фотонного кристалла с дефектом 单维光子晶体缺陷转角传感器
Pub Date : 2023-01-01 DOI: 10.21883/os.2023.07.56141.4568-23
Алексей Иванович Сидоров, Александр Александрович Ефимов
Представлены результаты численного моделирования оптических свойств одномерного (1D) фотонного кристалла с дефектом на основе слоев полупроводник-диэлектрик в ближнем ИК диапазоне. При моделировании использовались слои кремния и диоксида кремния с оптической толщиной 3λ/4, λ/4 и 10λ/4. Изучено влияние угла падения излучения на спектральное положение полосы пропускания дефекта. Показано, что чувствительность к углу поворота лежит в пределах 6-20 nm/deg и 1.7-5.5 dB/deg в зависимости от геометрии датчика и метода измерений. Это делает данные фотонные кристаллы перспективными для использования в датчиках угла поворота в качестве чувствительного элемента. Ключевые слова: датчик угла поворота, угол падения, фотонный кристалл, фотонная запрещенная зона, передаточная матрица.
在近红外范围内,基于半导体介质层的光晶体(1D)有缺陷的数值模拟结果。在模拟中使用了硅和二氧化硅层,光学厚度为3 /4、4和10 /4。研究辐射入射角对缺陷带光谱位置的影响。转角敏感度为6-20 nm/deg和1.7-5.5 dB/deg,视传感器几何和测量方法而定。这使得光子晶体很有可能在转角传感器中用作敏感元素。关键字:转角传感器,下降角度,光子晶体,光子禁区,传输矩阵。
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引用次数: 0
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Оптика и спектроскопия
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