Electrical conduction phenomena of oil/polymer systems

S. Ochiai, H. Iwasaki, T. Mizutani, M. Ieda
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Abstract

Oil-polymer interactions were investigated using various combinations of polymer and oil. The current magnitudes in oil-polymer systems were in the following order: LDPE>HDPE>PP>PET>>FEP. These results are discussed, considering the solubility parameter (SP), the crystallinity of the polymer, and impurities in the polymer. It was found that the magnitude of the charging current in oil-polymer systems cannot be explained by the SP value alone. It is affected by impurities in the polymer (including antioxidant) close to the oil-polymer interface. Antioxidant is extracted from the polymer during sulfuric acid treatment. The treatment of sulfuric acid reduces the current and changes the TSC (thermally stimulated current) spectrum.<>
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油/聚合物体系的导电现象
采用不同的聚合物和油的组合研究了油-聚合物的相互作用。目前在油-聚合物体系中的含量为:LDPE>HDPE>PP>PET> FEP。考虑到溶解度参数(SP)、聚合物的结晶度和聚合物中的杂质,对这些结果进行了讨论。发现油聚合物体系中充电电流的大小不能仅用SP值来解释。它受靠近油-聚合物界面的聚合物中杂质(包括抗氧化剂)的影响。在硫酸处理过程中从聚合物中提取抗氧化剂。硫酸的处理降低了电流并改变了TSC(热激电流)谱。
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