Properties of MoS2-based hydrotreating catalysts modified by electron donor or electron acceptor additives (P, Na, Cs, F)

R. Hubaut, O. Poulet, S. Kasetelan, E. Payen, J. Grimblot
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Abstract

The hydrotreating reactions performed under high hydrogen pressure constitute an important part in the petroleum refining for producing clean fuels adapted to the market. The aim of this study is to obtain correlations between the catalytic results (activity and selectivity) and some chemical and structural characteristics of sulfided catalysts in which electron donor or acceptor elements have been added to the MoS 2 -Al 2 O 3 standard formulation. Experimental results are presented and discussed. It is deduced that additives like phosphorus, alkaline ions or fluorine have some effects on this catalyst.
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电子给体或电子受体添加剂(P, Na, Cs, F)改性二硫化钼基加氢处理催化剂的性能
在高氢气压力下进行的加氢处理反应是石油炼制生产适应市场的清洁燃料的重要组成部分。本研究的目的是获得在MoS 2 -Al 2o3标准配方中加入电子供体或电子受体元素的硫化催化剂的催化结果(活性和选择性)与某些化学和结构特征之间的相关性。给出了实验结果并进行了讨论。推断出磷、碱性离子或氟等添加剂对该催化剂有一定的影响。
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