Analysis of Flows of Polymeric Solutions and Liquid Crystals

N. Mori
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Abstract

Flows of polymeric fluids and liquid crystalline polymers (LCPs) were studied in complex flow geometries. In the present paper, however, there is a focus on the flow analysis of the flow of LCPs. Numerical simulations of flows of LCPs were carried out using the modified Doi equation with the quadratic closure approximation. Molecular orientation of LCPs is strongly affected by the velocity field including both the shear and elongational flows in the complex geometry while the velocity distribution is modified by the molecular orientation. Numerical simulations for a flow between parallel plates containing a cylinder and a spinning flow are presented as examples. A novel rubbing-free alignment layer for LCs was proposed as an application of flow-induced molecular orientation of LCPs. The development of wavy texture in startup flows of LCPs through a slit cell was discussed.
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聚合物溶液和液晶流动分析
研究了聚合物流体和液晶聚合物(lcp)在复杂流动几何中的流动。然而,在本文中,重点是对lcp流动的流动分析。采用改进的Doi方程和二次闭包近似对lcp的流动进行了数值模拟。在复杂几何结构中,剪切流和拉伸流两种速度场对lcp的分子取向都有强烈的影响,而分子取向则改变了lcp的速度分布。给出了含圆柱平行板间流动和旋转流动的数值模拟实例。提出了一种新型的无摩擦液晶取向层,用于液晶的流动诱导分子取向。讨论了lcp通过狭缝池启动流动时波纹织构的发展。
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