Block catalytic system for neutralization of carbon monoxide based on aerated concrete

V. Radovenchyk, O. Ivanenko, Аnton Karvatskii, Іgor Mikulionok, Serhii Plashykhin, Tetiana Overchenko, Yuliia Nosachova, S. Dovholap
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Abstract

The paper presents the results of a study of catalysts for the conversion of carbon monoxide based on aerated concrete, modified with magnetite and chromium ferrite separately and in aggregate. It was found that at a consumption of 100 g of catalyst powder per 1 dm3 of a typical mixture for producing aerated concrete and obtaining blocks of modified aerated concrete according to the traditional technology, their efficiency is 70-85% at 400 °C and decreases to 9-13% at 200 °C. In terms of strength and physicochemical properties, aerated concrete samples differ little from standard ones, and in some cases even exceed them. The proposed method for fixing catalyst particles in blocks of aerated concrete makes it possible to build fundamentally new schemes for neutralizing carbon monoxide when placing modified blocks directly at the loading of electrode raw materials in furnaces. This greatly simplifies the conversion process and its control system.
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以加气混凝土为基础的中和一氧化碳的嵌段催化系统
本文介绍了以磁铁矿和铁酸铬分别改性和集料改性加气混凝土为原料的一氧化碳转化催化剂的研究结果。研究发现,在生产加气混凝土和按传统工艺获得改性加气混凝土块料的典型混合料中,每1 dm3消耗100 g催化剂粉时,其效率在400℃时为70-85%,在200℃时下降到9-13%。在强度和理化性能方面,掺气混凝土试样与标准试样相差不大,有的甚至超过标准试样。所提出的将催化剂颗粒固定在加气混凝土块中的方法,使得在将改性块直接放置在炉中电极原料的装载处时,可以建立根本的新方案来中和一氧化碳。这大大简化了转换过程及其控制系统。
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