Cyclopropanation of polyvinyl alcohol

K. G. Guliyev, V. E. Vakhabova
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Abstract

The esterification reaction of polyvinyl alcohol with para-aminophenylcyclopropane carboxylic acyl chloride has been studied in order to obtain a diversified polymer containing fragments of polyvinyl alcohol and groups, amino and cyclopropane rings, as well as other fragments in the side links of the macromolecule. As a result of the study, a new polymer was synthesized and its composition and structure were determined on the basis of IR and NMR spectroscopy data. The properties of the synthesized polymer have been studied and it has been established that the modified polymer has high antimicrobial properties, which makes it possible to use it as an antimicrobial substance in medicine.
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聚乙烯醇的环丙烷化
研究了聚乙烯醇与对氨基苯基环丙烷羧基酰氯的酯化反应,得到了含有聚乙烯醇和基团片段、氨基环和环丙烷环以及大分子侧链上其他片段的多样化聚合物。研究结果合成了一种新型聚合物,并根据红外和核磁共振光谱数据确定了其组成和结构。对所合成聚合物的性能进行了研究,确定改性后的聚合物具有较高的抗菌性能,使其有可能在医学上用作抗菌物质。
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