New stabilizer Cellulose Nano Rods-Zinc Oxide (CNR-ZnO) material for nanocomposite synthesis and anti-bacterial applications

W. Aziz, R. Hussain, I. A. Ibraheem
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引用次数: 1

Abstract

Zinc oxide (ZnO) nanorods were fabricated using Cellulose Nano Rods (CNR) as a new stabilizer material. Synthesized of ZnO-CNR nanocomposites, with a molar ratio of ZnO to CNR (1/2g) were prepared in distilled water. The nanocomposites were distinguished using X-ray diffraction (XRD), ultraviolet-visible (UV-Vis), and Field Emission scanning electron microscope (FESEM) techniques. XRD data were showed, the ZnO nanorods with a hexagonal wurtzite structure such readily scattered inside CNR with an average size 20-40 nm. (FESEM) images showed the homogenous morphology of Zinc oxide rods. The optimum ratio of ZnO-CNR was selected to be the tiny size of the ZnO nanorods that yielded a good stabilizer material and antibacterial activity. The ultraviolet-visible (UV-Vis) absorption spectrum of the ZnO-CNR nanocomposites appeared absorption peaks in the ultraviolet region at (350-360 nm) wavelength attributes with the energy gap of (3.41 eV) of ZnO-CNR. The antibacterial activities of samples have been investigated against the Gram-positive ( pneumonia ) and gram-negative ( pseudomonas ). The maximum antibacterial activities against the Gram-positive ( pneumonia ) of ZnO nanorods and of ZnO- cellulose nanorods are 16 mm and 22 mm respectively. The optimum anti-bacterial activities versus the Gram-negative ( pseudomonas ) of zinc oxide nanorods and zinc oxide- cellulose nanorods are 17 mm and 19 mm respectively. The optimum anti-bacterial activities versus the Gram-negative ( pseudomonas ) of zinc oxide nanosheet and of zinc oxide- cellulose nanorods are 17 mm and 22 mm.
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新型稳定剂纤维素纳米棒-氧化锌(CNR-ZnO)材料用于纳米复合材料的合成和抗菌应用
以纤维素纳米棒(CNR)为稳定剂制备氧化锌纳米棒。在蒸馏水中制备了ZnO与CNR摩尔比为1/2g的ZnO-CNR纳米复合材料。采用x射线衍射(XRD)、紫外可见(UV-Vis)和场发射扫描电子显微镜(FESEM)对纳米复合材料进行了表征。XRD数据表明,具有六方纤锌矿结构的ZnO纳米棒易于分散在CNR内部,平均尺寸为20 ~ 40 nm。(FESEM)图像显示氧化锌棒形貌均匀。选择ZnO- cnr的最佳配比,制备的ZnO纳米棒尺寸小,具有良好的稳定材料和抗菌活性。ZnO-CNR纳米复合材料的紫外-可见(UV-Vis)吸收光谱在(350 ~ 360 nm)紫外区出现吸收峰,ZnO-CNR的能隙为(3.41 eV)。研究了样品对革兰氏阳性(肺炎)和革兰氏阴性(假单胞菌)的抑菌活性。氧化锌纳米棒和氧化锌-纤维素纳米棒对革兰氏阳性(肺炎)的最大抑菌活性分别为16 mm和22 mm。氧化锌纳米棒和氧化锌纤维素纳米棒对革兰氏阴性菌(假单胞菌)的最佳抑菌活性分别为17 mm和19 mm。氧化锌纳米片和氧化锌纤维素纳米棒对革兰氏阴性菌(假单胞菌)的最佳抑菌活性分别为17 mm和22 mm。
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