Development of New Eco-Composites From Natural Agro-Residues and Recycled Polymers

K. Alzebdeh, M. Nassar, Nasr Al-Hinai
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引用次数: 1

Abstract

Wood plastic composite materials have shown a remarkable performance in various applications due to its inherent properties like strength, durability, and lightweight over conventional composite materials. However, utilization of wood as an organic filler for polymers poses a serious negative impact to the green areas. Therefore, utilization of agro-residues as organic fillers instead of wood offers a sustainable solution to the aforementioned problem. In this context, this study aims to investigate the potential use of date palm pedicel agro-residues as natural fillers in eco-composites in which recycled post-consumer polypropylene is used as a matrix. Three levels of date palm flour content, namely, 10 v.%, 20 v.% and 30 v.% are used. The influence of the date palm pedicels flour content on the mechanical, physical and thermal behavior of the developed eco-composites is examined. Material properties of the fabricated eco-composites are characterized experimentally according to ASTM standards. Thermogravimetric analysis (TGA) is also performed to assess the thermal decomposition of the developed composites. Moreover, the morphology of fractured regions is captured using Scanning Electron Microscope (SEM). Generally, adding natural fillers to the polymer matrix is a cost effective option. However, it also slightly affects tensile strength, elongation, and flexural strength at break and enhance the Young’s modulus compared to the neat polypropylene. Interestingly, it is observed that the recycled polypropylene based composites are more repellent to water absorption in comparison to the virgin polypropylene-based composites. This attribute might be due to the surface quality transformation for the reprocessed plastic polymer.
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新型生态复合材料的研究进展
木塑复合材料由于其固有的性能,如强度、耐久性和重量轻于传统复合材料,在各种应用中表现出卓越的性能。然而,利用木材作为聚合物的有机填料对绿地造成了严重的负面影响。因此,利用农业残留物作为有机填料代替木材为上述问题提供了一个可持续的解决方案。在这种情况下,本研究的目的是研究椰枣梗农业残留物作为生态复合材料的天然填料的潜在用途,其中回收的消费后聚丙烯被用作基质。使用了三个等级的椰枣粉含量,即10v %、20v %和30v %。研究了红枣皮粉含量对生态复合材料力学、物理和热性能的影响。根据ASTM标准对制备的生态复合材料的材料性能进行了实验表征。热重分析(TGA)也进行了评估开发的复合材料的热分解。此外,利用扫描电子显微镜(SEM)捕获了断裂区域的形貌。通常,在聚合物基体中添加天然填料是一种经济有效的选择。然而,与纯聚丙烯相比,它也略微影响拉伸强度、伸长率和断裂时的弯曲强度,并提高杨氏模量。有趣的是,观察到回收的聚丙烯基复合材料比原始聚丙烯基复合材料更排斥吸水。这种特性可能是由于再加工塑料聚合物的表面质量变化。
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