MOLECULAR INTERACTIONS OF L-TYROSINE IN DIMETHYL SULFOXIDE AQUEOUS SOLUTIONS. PART 1: ELECTRONIC ABSORPTION AND FLUORESCENCE SPECTROSCOPY STUDIES

K. Grigoryan, H. Shilajyan, Roza G. Harutyunyan
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Abstract

Molecular interactions of L-tyrosine in dimethyl sulfoxide (DMSO) aqueous solutions have been studied using electronic absorption and fluorescence spectro¬scopy methods. It has been shown that at low concentrations of DMSO in aqueous media hetero-associates such as 1DMSO:1H2O or 1DMSO:2H2O are formed, while at high concentrations, associates of a more complex structure (mixed clusters) are formed that interact with L-tyrosine to form complex compounds.
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l -酪氨酸在二甲基亚砜水溶液中的分子相互作用。第1部分:电子吸收和荧光光谱研究
用电子吸收和荧光光谱法研究了l -酪氨酸在二甲基亚砜(DMSO)水溶液中的分子相互作用。研究表明,在低浓度的DMSO水溶液中,会形成异缔合物,如1DMSO:1H2O或1DMSO:2H2O,而在高浓度下,会形成更复杂结构的缔合物(混合簇),与l -酪氨酸相互作用形成复杂的化合物。
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