Performance of electrode materials during food processing by pulsed electric fields

A. Gad, S. Jayaram, M. Pritzker
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引用次数: 6

Abstract

Food processing by pulsed electric fields (PEFs) is a promising non-thermal method for increasing the shelf-life of liquid food products such as milk, juices and beer. Maintaining both the fresh-like taste and the original nutritional value makes PEF processing advantageous over conventional thermal pasteurization1. However, physical contact between the liquid food and the metallic electrodes during the PEF process is unavoidable and causes some metallic ions to be released from the electrodes into the processed food. The released metallic ions represent a challenging problem for this technology because they may affect the taste of the processed food and/or they reduce the life-time of the electrodes.This study is to evaluate the performance of various metals used as the electrodes by comparing the rates of release of metallic ions from chromium, nickel, silver and titanium as well as conventional stainless steel during PEF processing. The concentration of metallic ions in PEF-processed food products are measured using inductively coupled plasma - atomic emission spectrometry (ICP-AES). The first objective of the work is to rank the materials by taking into account both the price and the life-time of each material. This ranking is carried out for a variety of food products having different values of pH and electrical conductivity. Both the rate and price of replacing the electrodes should be considered when assessing the economic feasibility of the PEF process. By investigating the physical and chemical properties of the electrode materials used, the second objective of the work aims to understand more about the mechanism by which the metallic ions are released. Under the extreme conditions of voltage and current applied during typical PEF processing, the classical electrochemical theories may not be sufficient. Understanding more about the mechanism may provide a new basis for better selection of electrode materials.
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脉冲电场对食品加工中电极材料性能的影响
脉冲电场(PEFs)食品加工是一种很有前途的非热方法,可以延长液体食品(如牛奶、果汁和啤酒)的保质期。保持新鲜的味道和原有的营养价值使PEF处理优于传统的热巴氏灭菌1。然而,在PEF过程中,液态食品与金属电极之间的物理接触是不可避免的,并导致一些金属离子从电极释放到加工食品中。释放的金属离子对这项技术来说是一个具有挑战性的问题,因为它们可能会影响加工食品的味道和/或缩短电极的寿命。本研究通过比较PEF加工过程中铬、镍、银、钛和传统不锈钢中金属离子的释放速率,来评价用作电极的各种金属的性能。采用电感耦合等离子体原子发射光谱法(ICP-AES)测定了pef加工食品中金属离子的浓度。这项工作的第一个目标是通过考虑每种材料的价格和使用寿命来对材料进行排名。这一排名是针对具有不同pH值和电导率的各种食品进行的。在评估PEF工艺的经济可行性时,应考虑更换电极的速度和价格。通过研究所使用的电极材料的物理和化学性质,这项工作的第二个目标旨在更多地了解金属离子释放的机制。在典型PEF加工过程中所施加的电压和电流的极端条件下,经典的电化学理论可能是不够的。对其机理的进一步了解可以为更好地选择电极材料提供新的依据。
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