Physical-chemical transformations in the system V2O5/(NH4)2Mo2O7 under hydrothermal conditions

S. Khalameida, V. Sydorchuk, R. Leboda, J. Skubiszewska-Zięba, V. Zazhigalov
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引用次数: 4

Abstract

AbstractModified compositions in the system V2O5/(NH4)2Mo2O7 have been prepared by means of mechanochemical, hydrothermal, microwave and ultrasonic treatments in aqueous medium. Chemical and phase transformations occurring on the stages of modification and following calcinations have been studied with the help of XRD, DTA-TG, FTIR and UV-Vis spectroscopy, nitrogen adsorption, and SEM. It has been established that precursors of catalytically active phases possessing meso-macroporous structure have been formed during modification. The comparison of the properties of compositions prepared via different methods has been carried out. Particularly, precursors modified via various procedures possess different morphology.
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水热条件下V2O5/(NH4)2Mo2O7体系的物理化学转变
摘要在水介质中采用机械化学、水热、微波和超声波等方法制备了V2O5/(NH4)2Mo2O7体系的改性组分。利用XRD、DTA-TG、FTIR、UV-Vis光谱、氮气吸附、SEM等研究了改性和煅烧过程中发生的化学和相变。在改性过程中形成了具有介孔-大孔结构的催化活性相前驱体。对不同方法制备的组合物的性能进行了比较。特别是,通过各种方法修饰的前体具有不同的形态。
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