V. Rodrigues, M. M. Costa, E. Gomes, D. Isakov, M. Belsley
{"title":"L-alaninium perrhenate: crystal structure and non-linear optical properties","authors":"V. Rodrigues, M. M. Costa, E. Gomes, D. Isakov, M. Belsley","doi":"10.2478/s11532-014-0548-9","DOIUrl":null,"url":null,"abstract":"AbstractThe crystal structure and non-linear optical properties of L-alaninium perrhenate, C3H8NO2+ ReO4−, are reported. The protonated amino acid and the perrhenate anion have their usual geometries. The three-dimensional hydrogen-bonded network can be seen as a stacking of layers parallel to the (100) planes. Each layer is formed by chains of alternating positive and negative ions along the b and c axes. Hydrogen bonding of adjacent layers forms alternating chains along the a axis. A high damage threshold and a second-harmonic generation efficiency three times that of KDP make this new material potentially useful in non-linear optics.\n","PeriodicalId":9888,"journal":{"name":"Central European Journal of Chemistry","volume":"3 1","pages":"1016-1022"},"PeriodicalIF":0.0000,"publicationDate":"2014-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Central European Journal of Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2478/s11532-014-0548-9","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
AbstractThe crystal structure and non-linear optical properties of L-alaninium perrhenate, C3H8NO2+ ReO4−, are reported. The protonated amino acid and the perrhenate anion have their usual geometries. The three-dimensional hydrogen-bonded network can be seen as a stacking of layers parallel to the (100) planes. Each layer is formed by chains of alternating positive and negative ions along the b and c axes. Hydrogen bonding of adjacent layers forms alternating chains along the a axis. A high damage threshold and a second-harmonic generation efficiency three times that of KDP make this new material potentially useful in non-linear optics.
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