M. Beck, Paul Birnbrich, U. Eicken, H. Fischer, William E. Fristad, Brigitte Hase, H. Krause
{"title":"Polyoxazoline auf fettchemischer Basis","authors":"M. Beck, Paul Birnbrich, U. Eicken, H. Fischer, William E. Fristad, Brigitte Hase, H. Krause","doi":"10.1002/APMC.1994.052230116","DOIUrl":null,"url":null,"abstract":"A new, economic techniques was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of ΔH= 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline","PeriodicalId":7808,"journal":{"name":"Angewandte Makromolekulare Chemie","volume":"28 1","pages":"217-233"},"PeriodicalIF":0.0000,"publicationDate":"1994-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"38","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Makromolekulare Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/APMC.1994.052230116","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 38
Abstract
A new, economic techniques was developed for the production of 2-alkyl-2-oxazolines with saturated, unsaturated or OH-functionalized alkylrests. In the process the fatty acids are changed into polymerizable monomers. The cationic polymerization of fattyalkyl-2-oxazolines was investigated in unpolar solvents and in bulk. It reacts in a living mechanism. The polymerization is remarkable inert against impurities like water or ethanolamide. A reaction enthalpy of ΔH= 85,9 kJ/mol was found for the bulk polymerization of 2-pentadecyl-2-oxazoline
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