Surfactant Modified Graphene Oxide for the Detection of Dopamine

Diptesh G. Naik, B. R. Naik, Akshay V. Salkar, Vrushali S. Joshi
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Abstract

A synthesis and characterization of a surfactant functionalize graphene oxide, and its potential applications for biosensor are presented. Graphene oxide was prepared using improved Hummer′s method and modified with two different surfactants viz. cetyltrimethylammonium bromide (CTAB) and Sodium dodecyl sulfate (SDS) by chemical method. The formation of the product was confirmed by characterizing it with UV-Viz, IR spectroscopy and Scanning electron microscopy (SEM). Here, we report simple and low cost method to develop electrochemical dopamine sensor by drop-casting catalysts on graphite rod conducting phase. A developed sensor is used for the voltammetric detection of the micro - millimolar quantity of dopamine without any fouling of electrode surface. The kinetics of electron transfer in the dopamine oxidation reaction on the surface of a catalysts are investigated.
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表面活性剂修饰氧化石墨烯对多巴胺的检测
介绍了一种功能化氧化石墨烯表面活性剂的合成、表征及其在生物传感器中的潜在应用。采用改进的Hummer法制备氧化石墨烯,并用十六烷基三甲基溴化铵(CTAB)和十二烷基硫酸钠(SDS)两种不同的表面活性剂进行化学修饰。用紫外光谱、红外光谱和扫描电镜对产物进行了表征,证实了产物的形成。本文报道了在石墨棒导电相上滴铸催化剂制备电化学多巴胺传感器的简单、低成本方法。该传感器可在不污染电极表面的情况下对微毫摩尔多巴胺量进行伏安检测。研究了催化剂表面多巴胺氧化反应的电子转移动力学。
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