{"title":"A modification to the ferrioxalate actinometer","authors":"K. C. Kurien","doi":"10.1039/J29710002081","DOIUrl":null,"url":null,"abstract":"When a solution of potassium ferrioxalate containing 0·02% of o-phenanthroline monohydrate and acetate buffer (final pH 3·7) is irradiated with 2537 and 3650 A light, the absorbance at 5100 A due to the formation of the ferrous o-phenanthroline complex has been found to increase linearly with dose. The suitability of this system as a more convenient chemical actinometer is discussed here.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"459 1","pages":"2081-2082"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"41","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710002081","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 41
Abstract
When a solution of potassium ferrioxalate containing 0·02% of o-phenanthroline monohydrate and acetate buffer (final pH 3·7) is irradiated with 2537 and 3650 A light, the absorbance at 5100 A due to the formation of the ferrous o-phenanthroline complex has been found to increase linearly with dose. The suitability of this system as a more convenient chemical actinometer is discussed here.
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