Non-parametric calibration of multiple related radiocarbon determinations and their calendar age summarisation

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2022-10-17 DOI:10.1111/rssc.12599
Timothy J. Heaton
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引用次数: 1

Abstract

Due to fluctuations in past radiocarbon ( 14 $$ {}^{14} $$ C) levels, calibration is required to convert 14 $$ {}^{14} $$ C determinations X i $$ {X}_i $$ into calendar ages θ i $$ {\theta}_i $$ . In many studies, we wish to calibrate a set of related samples taken from the same site or context, which have calendar ages drawn from the same shared, but unknown, density f ( θ ) $$ f\left(\theta \right) $$ . Calibration of X 1 , , X n $$ {X}_1,\dots, {X}_n $$ can be improved significantly by incorporating the knowledge that the samples are related. Furthermore, summary estimates of the underlying shared f ( θ ) $$ f\left(\theta \right) $$ can provide valuable information on changes in population size/activity over time. Most current approaches require a parametric specification for f ( θ ) $$ f\left(\theta \right) $$ which is often not appropriate. We develop a rigorous non-parametric Bayesian approach using a Dirichlet process mixture model, with slice sampling to address the multi-modality typical within 14 $$ {}^{14} $$ C calibration. Our approach simultaneously calibrates the set of 14 $$ {}^{14} $$ C determinations and provides a predictive estimate for the underlying calendar age of a future sample. We show, in a simulation study, the improvement in calendar age estimation when jointly calibrating related samples using our approach, compared with calibration of each 14 $$ {}^{14} $$ C determination independently. We also illustrate the use of the predictive calendar age estimate to provide insight on activity levels over time using three real-life case studies.

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多个相关放射性碳测定的非参数校准及其日历年龄汇总
由于过去放射性碳(14 $$ {}^{14} $$ C)水平的波动,需要校准转换14 $$ {}^{14} $$ C测定X i$$ {X}_i $$变成历法年龄θ I $$ {\theta}_i $$。在许多研究中,我们希望校准来自同一地点或环境的一组相关样本,这些样本的日历年龄来自相同的共享但未知的密度f (θ) $$ f\left(\theta \right) $$。校准x1,…,X n $$ {X}_1,\dots, {X}_n $$可以通过纳入样本相关的知识而得到显著改善。此外,对潜在的共享f (θ) $$ f\left(\theta \right) $$的概要估计可以提供关于人口规模/活动随时间变化的有价值的信息。目前的大多数方法都需要f (θ) $$ f\left(\theta \right) $$的参数说明,这通常是不合适的。我们使用Dirichlet过程混合模型开发了严格的非参数贝叶斯方法,并使用切片采样来解决14 $$ {}^{14} $$ C校准内的多模态典型问题。我们的方法同时校准了14个$$ {}^{14} $$ C测定集,并为未来样本的潜在日历年龄提供了预测性估计。在一项模拟研究中,我们表明,与单独校准每个14 $$ {}^{14} $$ C测定相比,使用我们的方法联合校准相关样品时,日历年龄估计的改善。我们还通过三个现实案例研究说明了预测性日历年龄估计的使用,以深入了解随时间变化的活动水平。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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