Optimization of Corrosion Inhibitor for a Gas and Condensate Field

S. Hirano, Toshiyuki Sunaba, Kazuyo Sasaya, Atsushi Kobayashi, Hirokazu Yorozu, H. Iijima
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Abstract

Qualification of a new corrosion inhibitor was carried out for both tubing and flowline services in a gas and condensate field because the production condition changed. The methodology and result of the inhibitor evaluation under a sweet condition was summarized. The depth of production well is 4,500 m and the bottom hole temperature and pressure are 180 °C and 50 MPa respectively. Two brands of corrosion inhibitors had been used for production tubing and flowline respectively in the field. A new inhibitor was investigated for the both applications. The performance of corrosion inhibitor efficiency was evaluated with a rotating cage autoclave. In order to evaluate the tendency of emulsion forming, Oil, brine and an inhibitor were poured into a centrifuge tube and it was shaken intensely. Gas chromatograph - mass spectrometer (GC-MS) and Fourier transform infrared spectroscopy (FT-IR) were studied to measure the residual amount of inhibitor. Finally the field trial was carried out with the new inhibitor. The new inhibitor was adopted successfully for the both services. The GC-MS analysis showed the flow back lasted more than two hours. The risk of emulsion forming became lower because the mixing of two brands of inhibitors was avoided. Reducing the number of the chemicals contributed to reduction of the operation cost too.
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某凝析气田缓蚀剂的优化
由于生产条件发生了变化,对一种新型缓蚀剂进行了鉴定,适用于天然气和凝析油田的油管和管线服务。综述了甜条件下缓蚀剂评价的方法和结果。生产井深度4500 m,井底温度180℃,井底压力50 MPa。两种品牌的缓蚀剂分别用于生产油管和管线。为这两种应用研究了一种新的抑制剂。用旋转笼式高压灭菌器对缓蚀剂的性能进行了评价。为了评价乳化液的形成趋势,将油、盐水和一种抑制剂倒入离心管中并剧烈摇动。采用气相色谱-质谱联用(GC-MS)和傅里叶变换红外光谱(FT-IR)测定缓蚀剂残留量。最后对该抑制剂进行了现场试验。新抑制剂成功应用于两种服务。GC-MS分析显示回流持续2小时以上。由于避免了两种抑制剂的混合,乳化形成的风险降低了。减少化学品的数量也有助于降低操作成本。
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