The effect of chemical composition on the biodegradation rate and physical and mechanical properties of polymer composites with lignocellulose fillers

V. Glukhikh, A. Shkuro, P. Krivonogov
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Abstract

The results of TPLC scientific research, practical experience of their preparation, and application as of 2016 are presented in eight volumes of the “Handbook of Composites from Renewable Materials” (2017, John Wiley & Sons, Inc.). This article provides an analysis of books and articles with open access to the Science Direct (Elsevier) database for the period 2017–2020 to assess the biodegradation rate and physical and mechanical properties of polymer composites with lignocellulosic fillers. The production and use of polymer composites with a thermoplastic polymer matrix and lignocellulosic fillers (TPLC) have significant ecological and eco- nomic prospects since waste biomass from forests, agriculture, and polymers obtained from petroleum raw materials can be used for their production. However, depending on the TPLC application area, there are opposite requirements for the biodegradation rate. For the use in construction and medicine materials and products must have a minimum biodegradation rate. Materials and products for single-use packaging must have the necessary biodegradability potential and have an adjusted biodegradation rate in soil, water, compost environment. Research results show that the properties of TPLC can be significantly influenced not only by the physical but also by the chemical structure of all components of these composites. The chemical properties of polymers, fillers, additives for various purposes can affect their industrial production efficiency.
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化学成分对木质纤维素填充聚合物复合材料生物降解率和物理力学性能的影响
截至2016年,TPLC的科学研究成果、制备实践经验和应用在《可再生材料复合材料手册》(2017年,John Wiley & Sons, Inc.)的八卷中进行了介绍。本文对Science Direct (Elsevier)数据库2017-2020年开放访问的书籍和文章进行了分析,以评估木质纤维素填料聚合物复合材料的生物降解率和物理机械性能。热塑性聚合物基体和木质纤维素填料(TPLC)聚合物复合材料的生产和使用具有重要的生态和经济前景,因为来自森林、农业的废弃生物质和从石油原料中获得的聚合物可用于其生产。然而,根据TPLC应用领域的不同,对生物降解率也有相反的要求。用于建筑和医药的材料和产品必须具有最低的生物降解率。用于一次性包装的材料和产品必须具有必要的生物降解潜力,并在土壤、水、堆肥环境中具有可调节的生物降解率。研究结果表明,TPLC的性能不仅受到复合材料各组分的物理结构的显著影响,而且受到其化学结构的显著影响。各种用途的聚合物、填料、助剂的化学性质会影响它们的工业生产效率。
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