Comparative study on electrochemical corrosion behavior of boronized X52 steel in 1 M HCl and H2SO4 solutions

Gougue Sliman, Zidelmel Sami, Rouibeh Abdelkader, Hossine Tassi
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引用次数: 1

Abstract

This paper investigates the effect of boronizing treatment on the corrosion resistance of API X52 steel. Borides were grown on API X52 steel in a powder mixture containing 5% B4C as a boron source, 5% NaBF4 as an activator, and 90% SiC as diluents for 4 hours at 950 °C. X-ray diffraction (XRD) analysis revealed that the sample's boride layer contains only Fe2B phases. The corrosion behavior of borided and unborided specimens was investigated using the Tafel extrapolation method in 1M HCl and H2SO4 solutions. The results show that borided specimens have better corrosion resistance than unboronized specimens. The formation of layers of protective iron borides reduces the corrodability of the steel in the borided specimens. Boronizing increased the corrosion resistances of X52 steel in HCl and H2SO4 by 23 and 77-fold, respectively.
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硼化X52钢在1m HCl和H2SO4溶液中电化学腐蚀行为的比较研究
研究了渗硼处理对API X52钢耐蚀性的影响。以5% B4C为硼源,5% NaBF4为活化剂,90% SiC为稀释剂的粉末混合物在API X52钢上生长4小时,温度为950℃。x射线衍射(XRD)分析表明,样品的硼化物层仅含有Fe2B相。采用Tafel外推法研究了渗硼和未渗硼试样在1M HCl和H2SO4溶液中的腐蚀行为。结果表明,渗硼试样比未渗硼试样具有更好的耐蚀性。保护性硼化铁层的形成降低了渗硼试样中钢的耐蚀性。渗硼使X52钢在HCl和H2SO4中的耐蚀性分别提高了23倍和77倍。
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