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Study of Mechanical-Elastic Parameters of Reservoir Rocks with Respect to the Purpose of Permanent CO2 Storage 基于CO2永久封存目的的储层岩石力学弹性参数研究
Pub Date : 2023-09-13 DOI: 10.56801/mme1013
Adam Lacman, Matěj Křístek, Patricie Karol, Martin Klempa
CO2 emissions are considered to be partly responsible for climate change. One of the available methods to reduce CO2 emissions is its storage in favorable rock structures, such as mined hydrocarbon deposits. Natural hermeticity is guaranteed with this reservoir structure. An increase in pressure conditions in the deposit, induced by long-term CO2 storage, can lead to the splitting of exposed rocks. It is therefore necessary to carry out geomechanical tests on available drill core samples. The presented article presents the results of laboratory research aimed at determining the mechanical-elastic parameters of reservoir rocks of a hydrocarbon deposit using non-destructive testing. The advantage of this method is the possibility of testing the given samples before and after exposure to CO2. The laboratory research carried out revealed significant differences in the measured mechanical-elastic parameters of the tested samples. Taking into account that samples of the consistent reservoir structure of the same deposit were tested, the necessity of detailed testing of geomechanical parameters arises. It was interpreted that the differences in mechanical-elastic parameters found by the research may be caused by differences in the lithological composition (for these purposes, XRD powder diffraction was implemented), or by mechanical disturbance given, for example, by fracture predisposed by structural-tectonic processes. Different humidity can also have an effect, or degree of saturation of the tested samples.
二氧化碳的排放被认为是造成气候变化的部分原因。减少二氧化碳排放的有效方法之一是将其储存在有利的岩石结构中,例如开采的碳氢化合物矿床。这种储层结构保证了天然的密封性。由于长期的二氧化碳储存,沉积物中压力条件的增加会导致裸露岩石的分裂。因此,有必要对现有岩心样品进行地质力学试验。本文介绍了利用无损检测方法测定油气储层岩石力学弹性参数的实验室研究结果。这种方法的优点是可以在暴露于CO2之前和之后测试给定样品。进行的实验室研究揭示了测试样品的测量力学弹性参数的显着差异。考虑到同一矿床的储层结构是一致的,因此有必要对地质力学参数进行详细的测试。据解释,研究发现的力学弹性参数的差异可能是由岩性组成的差异引起的(为此,采用了XRD粉末衍射),或者是由给定的力学扰动引起的,例如,由构造-构造过程导致的裂缝。不同的湿度也会对被测样品的饱和度产生影响。
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引用次数: 0
Mechanical and Thermal Properties of Polyurethane-Palm Fronds Ash Composites 聚氨酯-棕榈叶灰复合材料的力学和热性能
Pub Date : 2023-09-05 DOI: 10.56801/mme1003
None Ahmed J. Mohammed, None Einas A. Abood, None Mahir A. Jalal, None Ibrahim K. Ibrahim
The aim of the article is to study the influence of environmentally friendly palm frond ash on the mechanical and thermal properties of polyurethane used as filler. Various weight filler ratios with particle sizes around (125 μm) were examined and characterized using elongation, tensile strength, Young's modulus, compressive strength, average burning time, and infrared spectroscopy. The results showed that the addition of 20 wt.% palm frond ash powder significantly improved the hardness mixture by about 2.83 MPa. In addition to that, the highest value of the compressive strength of the polymer with the additive was recorded at 10 wt.%. Also, the most excellent value of Young’s modulus was 2 MPa at a ratio of 50 wt. %, as was the average burning time of about 33 sec. The mechanical properties of polyurethane were affected by adding palm frond ash, which increases the tensile and compressive strengths, making it suitable for use in many applications. Moreover, the environmentally friendly material reflects the benefits of waste recycling. The addition of filler affects the morphology and strengthens the brittleness. Additionally, the use of fly ash from palm frond combustion in the technology of polyurethane materials complies. Partial replacement of petrochemical components with waste filler also reduces the total energy consumption in producing PU composites.
本文的目的是研究环保型棕榈叶灰作为填料对聚氨酯力学性能和热性能的影响。采用延伸率、抗拉强度、杨氏模量、抗压强度、平均燃烧时间和红外光谱对粒径在(125 μm)左右的填料进行了表征。结果表明,添加20 wt.%的棕榈叶灰粉可显著提高混合料的硬度约2.83 MPa。此外,聚合物的抗压强度最高值记录在10 wt.%的添加剂。此外,杨氏模量的最佳值为2 MPa,比例为50 wt. %,平均燃烧时间约为33秒。添加棕榈叶灰会影响聚氨酯的机械性能,从而增加拉伸和抗压强度,使其适用于许多应用。此外,环保材料反映了废物回收的好处。填料的加入影响了材料的形貌,增强了材料的脆性。此外,在聚氨酯材料技术中使用棕榈叶燃烧产生的粉煤灰也符合要求。废填料部分替代石化组分也降低了生产PU复合材料的总能耗。
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引用次数: 0
Analysis of Friction stir processed surface quality of AA2098 aluminum alloy for aeronautical applications 航空用AA2098铝合金搅拌摩擦加工表面质量分析
Pub Date : 2023-08-16 DOI: 10.56801/mme1000
None Mauro Carta, None Pasquale Buonadonna, None Gianluca Marongiu, None Mohamad El Mehtedi
FSP is a relatively new technique that changes the microstructure on the surface of the material to improve mechanical properties in the desired zone. This study aimed to investigate the surface quality of AA2098 sheets after being subjected to friction stir processing under different conditions of feed rate and rotational speed. A DoE analysis was developed with two factors, feed rate and rotational speed, and three different levels of 75, 100, 125 mm/min and 1000, 1250, 1500 rpm respectively, in order to assess the processed surface quality. The Sa parameter was used to represent the surface quality in different zones of the process, near entrance tool, middle and near exit tool, and ANOVA analysis was conducted. The results indicated that only the position and feed rate have a statistical influence on surface roughness. Additionally, the surface quality is strongly affected by the position relative to the entrance of the tool and the side (retreating or advancing sides). The roughness was found to be significantly lower on the advancing side rather than on the retreating side.
FSP是一种相对较新的技术,它通过改变材料表面的微观结构来改善所需区域的机械性能。本研究旨在研究在不同进料速率和转速条件下,AA2098板材经搅拌摩擦加工后的表面质量。在75、100、125 mm/min和1000、1250、1500 rpm三个不同转速水平下,对加工表面质量进行了DoE分析。采用Sa参数表示加工过程中不同区域、近入口刀具、中间和近出口刀具的表面质量,并进行方差分析。结果表明,只有位置和进给速度对表面粗糙度有统计影响。此外,表面质量受到相对于刀具入口和侧面(后退或前进)的位置的强烈影响。发现前进侧的粗糙度明显低于后退侧。
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引用次数: 0
Review Of Grain Refinement Performance Of Aluminium Cast Alloys 铸铝合金晶粒细化性能研究进展
Pub Date : 2023-08-07 DOI: 10.56801/mme997
Badiâ AIT EL HAJ, Abederrazak Hamadellah, Aboubakr BOUAYAD, Charaf El Akili
Improving the utilization of aluminum grain refinement in industrial settings is a continual point of focus for research. Grain refinement serves the dual purpose of not only achieving a fine grain size, but also enhancing the mechanical properties of materials. Numerous researchers have dedicated significant efforts over the last decades to explore the grain refinement of aluminium alloys. There have been a number of studies relating to the mechanisms that explains the observed phenomena associated with grain refinement. The most commonly employed are grain refiners based on Al–Ti–B system. However, a limited efficiency of these grain refiners on aluminium silicon alloys with excessive Si and the effect of alloying elements have been noticed. The review examines the impact of the factors influencing grain refining behaviour of master alloys, including the effects of poisoning elements such as Si, Mg, Zr, and Sr. A large grain refiners used for enhancing the properties of aluminium silicon alloys are reviewed. An overview of new refiners has been given. Also, procedures for assessment of grain refinement have been examined.
提高铝晶粒细化在工业环境中的利用率一直是研究的重点。晶粒细化具有双重目的,不仅可以获得细小的晶粒尺寸,还可以提高材料的力学性能。在过去的几十年里,许多研究人员致力于探索铝合金的晶粒细化。已经有许多关于解释与晶粒细化相关的观察现象的机制的研究。最常用的是基于Al-Ti-B体系的谷物精炼机。然而,这些晶粒细化剂对含有过量硅的铝硅合金的效率有限,而且合金元素的影响也很明显。综述了影响中间合金晶粒细化行为的因素,包括Si、Mg、Zr和sr等中毒元素的影响。综述了用于提高铝硅合金性能的大型晶粒细化剂。对新型精炼器进行了概述。此外,还审查了评估谷物细化的程序。
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引用次数: 0
Air and Vacuum Annealing Effect on the Highly Conducting and Transparent Properties of the Undoped Zinc Oxide Thin Films Prepared by DC Magnetron Sputtering 空气和真空退火对直流磁控溅射制备的未掺杂氧化锌薄膜高导电和透明性能的影响
Pub Date : 2023-03-31 DOI: 10.56801/mme889
Lamia Radjehi, Linda Aissani, Abdelkader Djelloul, Abdenour Saoudi, Salim Lamri, Komla Nomenyo, Gilles Lerondel, Frédéric Sanchette
In this study, we aim to investigate the effect of zinc interstitials (Zni) and oxygen vacancies (VO) on the ZnO electrical conductivity. ZnO films were synthesized via DC magnetron sputtering process using pure Zn target in gases mixture of Ar/O2 = 80/17.5 (sccm). In order to improve the optical and electrical prosperities, the obtained films were subjected to air and vacuum annealing treatment. Several techniques such as field emission scanning electron microscopy (FESEM), Grazing Incidence X-ray Diffraction (GIXRD), Raman spectroscopy, photoluminescence spectroscopy (PL) and UV-visible were used to study the influence of heat treatment on structural and physical properties of ZnO films. Electrical conductivity of ZnO thin films was determined by measuring the sheet resistance and thickness of the films. XRD results confirm the synthesis of annealed ZnO films of the hexagonal structure with a preferential orientation along the (002) plane. The average crystallite size is altered between 22.6 to 28.4 nm dependent on the plan orientation of the ZnO film. Morphology and crystallinity of the ZnO structure could efficiently control the transmittance, electrical resistivity and optical band gap. As deposited ZnO film showed a lower electrical resistivity of 2.72×10-3 Ωcm due to the Zn-rich conditions. Under vacuum annealing, a combination of low resistivity (1.17×10-2 Ωcm) and better optical transmittance (87 %) are obtained. ZnO films developed in this study with high transmittance and low resistivity and good electro-optical quality supports their use in transparent and conductive electrode applications. The plan presentation was visualized using Vesta, with the lattice parameter set as follows: a = b = 3.249 Å; c = 5.207 Å; α = β = 90°; γ = 120°. Based on the construction and optimization of primitive cells, the supercells were constructed and then optimized. Finally, (002) and (103) planes were cut and the planar supercell structure was constructed. In order to make a plane representation for the solid bulk with 10 Å of thickness.
在这项研究中,我们的目的是研究锌间隙(Zni)和氧空位(VO)对ZnO电导率的影响。在Ar/O2 = 80/17.5 (sccm)的混合气体中,采用直流磁控溅射法制备了ZnO薄膜。为了提高薄膜的光学和电学性能,对薄膜进行了空气和真空退火处理。采用场发射扫描电镜(FESEM)、掠入射x射线衍射(GIXRD)、拉曼光谱(Raman)、光致发光光谱(PL)和紫外可见等技术研究了热处理对ZnO薄膜结构和物理性能的影响。通过测量ZnO薄膜的片电阻和薄膜厚度来确定ZnO薄膜的电导率。XRD结果证实了沿(002)平面优先取向的六方结构退火ZnO薄膜的合成。根据ZnO薄膜的平面取向,平均晶粒尺寸在22.6 ~ 28.4 nm之间变化。ZnO结构的形貌和结晶度可以有效地控制透射率、电阻率和光学带隙。由于富锌的条件,沉积的ZnO薄膜具有较低的2.72×10-3 Ωcm电阻率。在真空退火下,获得了低电阻率(1.17×10-2 Ωcm)和更好的透光率(87%)。本研究开发的ZnO薄膜具有高透射率、低电阻率和良好的电光质量,支持其在透明和导电电极中的应用。利用Vesta将平面呈现可视化,点阵参数设置为:a = b = 3.249 Å;C = 5.207 Å;α = β = 90°;γ = 120°。在原始细胞构建和优化的基础上,构建并优化了超级细胞。最后切割(002)和(103)平面,构建平面超级单体结构。为了使厚度为10 Å的固体体的平面表示。
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引用次数: 4
Structure and Properties of Graphite-Molybdenum Brazed Joints 石墨-钼钎焊接头的组织与性能
Pub Date : 2023-03-31 DOI: 10.56801/mme989
None S. Maksymova, None V. Voronov, None P. Kovalchuk, None A. Larionov
The paper presents the results of X-ray microspectral studies of dissimilar brazed joints of molybdenum with graphite. It is shown that during active brazing of graphite with molybdenum, mutual diffusion processes occur, and the adhesion-active brazing filler metals penetrates into graphite, and interacts with it, which leads to the formation of carbide phases. When using the Ti-Cr-V and Cu-Ti-Ni systems brazing filler metals, titanium carbides are formed. The zirconium carbides are formed, when using the brazing filler metals based on the Zr-Pd(Mo) systems and the CxMey(Mo, Cr) carbides are formed using the brazing filler metals of the Pd-Ni-Cr-Ge system. The results of tests for three-point bending showed that the using of Pd-Ni-Cr-Ge brazing filler metals provides stable strength at the level of 34-37 MPa, destruction occurs along graphite.
本文介绍了不同类型钼与石墨钎焊接头的x射线显微光谱研究结果。结果表明,在石墨与钼的活性钎焊过程中,发生了相互扩散过程,粘结活性钎料渗透到石墨中,并与石墨相互作用,形成碳化物相。当使用Ti-Cr-V和Cu-Ti-Ni系统钎焊填充金属时,形成碳化钛。使用基于Zr-Pd(Mo)体系的钎料可形成锆碳化物,使用基于Pd-Ni-Cr-Ge体系的钎料可形成CxMey(Mo, Cr)碳化物。三点弯曲试验结果表明,Pd-Ni-Cr-Ge钎料钎焊强度稳定在34 ~ 37 MPa,沿石墨方向发生破坏。
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引用次数: 1
Surface cracks growth for superalloy in a round bar under different loading 高温合金在不同载荷下的表面裂纹扩展
Pub Date : 2023-03-31 DOI: 10.56801/mme986
None M. Abdulrazzaq, None Mahmoud. A. Hassan
The main objective of this paper is to experimentally and numerically detect the surface cracks in the round bar for Ni-Al- 315 steel superalloy and calculate the crack depth which induces the sintering of these alloys. Several factors have contributed to surface defects, such as metallurgical defects and notches. The surface crack orientation can be estimated at the observed crack increase by using displacement. Various crack aspect ratios, a/b, ranging from 0.0 to 1.0, and relative crack depth, a/D, ranging from 0.2 to 0.4, are considered. The superalloy (Ni, Al and 315 steel) has been successfully modified utilizing the powder metallurgical process. The specimens are typically made up of Six layers, starting with (Al, Ni) across one side and ending with (Ni-Al- 315 steel) on another. Transmission electron microscopy (SEM) Instrument analysis has been used to detect the surface cracks and analyze the microstructure of superalloy used in detail using the X-pert analytical program.
本文的主要目的是对Ni-Al- 315钢高温合金圆棒表面裂纹进行实验和数值检测,并计算引起合金烧结的裂纹深度。有几个因素导致了表面缺陷,如冶金缺陷和缺口。利用位移法可以在观察到的裂纹增加处估计表面裂纹的方向。考虑了各种裂纹宽高比(a/b,范围从0.0到1.0)和相对裂纹深度(a/D,范围从0.2到0.4)。利用粉末冶金技术成功地对高温合金(Ni、Al和315钢)进行了改性。试样通常由六层组成,从(Al, Ni)开始横跨一侧,以(Ni-Al- 315钢)结束另一侧。采用透射电子显微镜(SEM)仪器分析方法对高温合金表面裂纹进行了检测,并用X-pert分析程序对其微观组织进行了详细分析。
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引用次数: 2
Preliminary study of two antique Illyrian helmets (V-IV B.C.) excavated in northwest and northeast of Albania 对在阿尔巴尼亚西北部和东北部出土的两个古代伊利里亚头盔(公元前V-IV)的初步研究
Pub Date : 2023-03-31 DOI: 10.56801/mme929
Olta Çakaj, None Nikolla Civici, None Gert Schmidt
This study combines several analytical techniques to preliminary investigate two Illyrian helmets (V-IV century B.C.) excavated in Nënshat (Shkodra, northwest Albania) and in Krumë (Has, northeast Albania). They were stored in the Center of Albanian Studies, after excavation in 1963 in damaged conditions but have never been studied until now. The aims of this paper are the investigation of the helmets’ alloy and production technique; hence SEM-EDS, OM and Vickers microhardness tester were used to study the elements content, microstructure inclusions and its characteristics due to the production process. The Illyrian helmets alloy resulted Cu-Sn with less than 1% of Fe and As. The microstructure was composed by straight and bended twins, with 160.5 and 169.6 mean Vickers microhardness values, suggesting that these objects’ alloys were casted, annealed and cold worked to obtain the final distinctive shape. Elements such as S, Si, Fe can originate from the copper mineral used for the alloy production. This paper is part of a campaign in Albania to better understand the past with the use of physical analytical techniques.
这项研究结合了几种分析技术,对出土于Nënshat(阿尔巴尼亚西北部的斯库德拉)和Krumë(阿尔巴尼亚东北部的Has)的两个伊利里亚头盔(公元前v - 4世纪)进行了初步调查。它们在1963年被挖掘出来后被保存在阿尔巴尼亚研究中心,但直到现在才被研究过。本文的目的是对钢盔的合金及生产工艺进行研究;利用SEM-EDS、OM和Vickers显微硬度计研究了合金的元素含量、显微夹杂物及其在生产过程中的特征。伊利里亚头盔合金的结果是Cu-Sn,铁和砷含量低于1%。显微组织由直孪晶和弯孪晶组成,显微硬度分别为160.5和169.6,表明这些合金经过铸造、退火和冷加工,最终获得了独特的形状。S、Si、Fe等元素可以来源于用于合金生产的铜矿物。本文是阿尔巴尼亚利用物理分析技术更好地了解过去的运动的一部分。
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引用次数: 0
In Situ Production of B4C and FeV Enriched Composite Surface on Low Carbon Steel by Cast Sintering Technique 用铸造烧结技术在低碳钢上原位制备B4C和FeV富集复合表面
Pub Date : 2023-03-31 DOI: 10.56801/mme913
Javkhlan Bat-Ulzii, Galaa Omoontsoo, Buryal Dondokovich Lygdenov, Tserenchimed Purevsuren
A simple and cost effective technique to obtain locally hardened composite layer on cast alloy was previously developed based on advantages of liquid-sintering theory. This methodology provides an opportunity to produce final product with hardened composite layer with good wear resistance during casting process. The current study investigated the effect of combined B4C and FeV substrates on the composite layer properties during in situ cast sintering technique for low carbon steel. Microstructure inspection, XRD phase analysis, chemical composition, thickness measurement and the hardness test on the produced composite layer were conducted. The technique produced up to 640 (±300) µm thick composite layer with maximum hardness of 481 (± 14.6) HV. The hardness of the reinforced surface layer is 3-4 times higher than the base alloy. The increased hardness of composite zone is directly attributed to the presence of the iron boron (FeB), boron vanadium (V2B3) and iron carbide (Fe3C). There were no significant effect of substrate composition on the produced thickness of the composite layer. However, an increase of FeV proportion in the powder mixture leads increased the hardness. The current study is a first attempt to produce locally hardened surface layer on the low carbon steel using simple and cost effective in situ technique with use of relatively inexpensive substrates.
基于液体烧结理论的优点,开发了一种简单、经济的铸造合金局部硬化复合层制备技术。这种方法为在铸造过程中生产具有良好耐磨性的硬化复合层的最终产品提供了机会。本研究研究了在低碳钢原位铸造烧结工艺中,B4C和FeV复合基体对复合层性能的影响。对制备的复合层进行了显微组织检查、XRD物相分析、化学成分测定、厚度测定和硬度测试。该技术可生产厚度达640(±300)μ m的复合层,最大硬度为481(±14.6)HV。增强面层硬度比基体合金高3-4倍。复合区硬度的提高直接归因于硼铁(FeB)、硼钒(V2B3)和碳化铁(Fe3C)的存在。衬底成分对制备的复合层厚度无显著影响。粉末混合物中FeV含量的增加使合金的硬度增加。目前的研究是第一次尝试使用简单和成本有效的原位技术,使用相对便宜的基材在低碳钢上生产局部硬化表面层。
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引用次数: 3
Dynamic Analyses of Two-Dimensional Functionally Graded Timoshenko Beam using Finite element Method 二维功能梯度Timoshenko梁的有限元动力分析
Pub Date : 2023-03-31 DOI: 10.56801/mme985
None Dhyai Hassan jawad Aljashaami, None Mohammed A Al-Shujairi, None Ameen M. Al Juboori, None Salwan Obaid Waheed Khafaji, None Mohammed Jawad Aubad
In this work, dynamic analyses of a functionally graded beam are presented. The governing equations of the beam is found based on the displacement field defined by Timoshenko beam theory, then solved by using finite element method based on Hamilton’s principle. The beam is assumed to be free-clambed boundary condition (F-C). The PL index is used for describing the distribution of the beam properties in both transverse and longitudinal directions. A parametric study is accomplished to investigate effect of several parameters on the natural frequency, mode shapes and transient response of the beam., such as the PL indexes (nx and nz) for x and z axis, respectively, and the elasticity modulus ratio (Eratio). To valid the present results and current mathematical formulation, some of the findings are compared with another research. A good agreement is noticed. It is noted that the response of the beam is more sensitive to the variations of the PI in the longitudinal axes than that corresponding in the transverse one. For specific design requirements, the dynamic response of the beam can be adjusted by chose a proposal indexes and modulus ratios.
本文对功能梯度梁进行了动力分析。根据Timoshenko梁理论定义的位移场,建立了梁的控制方程,并采用基于Hamilton原理的有限元方法进行求解。假定梁具有自由攀爬边界条件(F-C)。PL指数用于描述光束在横向和纵向上的特性分布。通过参数化研究,探讨了几种参数对梁的固有频率、振型和瞬态响应的影响。,分别为x轴和z轴的PL指数(nx和nz),以及弹性模量比(Eratio)。为了验证目前的结果和现有的数学公式,将一些发现与另一项研究进行了比较。一个好的协议被注意到了。结果表明,梁的响应对轴向PI的变化比轴向PI的变化更敏感。对于特定的设计要求,可以通过选择建议指标和模量比来调整梁的动力响应。
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引用次数: 1
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Metallurgical and Materials Engineering
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