Alexander I. Lebedev, I. Sluchinskaya, V. N. Demin, I. Munro
{"title":"Off-centering of Pb and Sn impurities in GeTe induced by strong local stress","authors":"Alexander I. Lebedev, I. Sluchinskaya, V. N. Demin, I. Munro","doi":"10.1051/JP4:19972172","DOIUrl":null,"url":null,"abstract":"Noncentrality of large impurity atoms—Pb and Sn atoms—substituting for Ge atoms in a GeTe lattice has been discovered by means of EXAFS investigations in Ge0.9Pb0.1Te and Ge0.85Sn0.15Te samples. The transition of impurity atoms into a noncentral position under conditions of a strong local stress is explained by the participation of an unshared electron pair from the impurity atoms in the formation of the chemical bond.","PeriodicalId":15816,"journal":{"name":"Journal of Experimental and Theoretical Physics Letters","volume":"247 1","pages":"635-638"},"PeriodicalIF":0.0000,"publicationDate":"1996-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Experimental and Theoretical Physics Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1051/JP4:19972172","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 23
Abstract
Noncentrality of large impurity atoms—Pb and Sn atoms—substituting for Ge atoms in a GeTe lattice has been discovered by means of EXAFS investigations in Ge0.9Pb0.1Te and Ge0.85Sn0.15Te samples. The transition of impurity atoms into a noncentral position under conditions of a strong local stress is explained by the participation of an unshared electron pair from the impurity atoms in the formation of the chemical bond.