A New Strategy for the Synthesis of Monomethylhydrazine Using the Raschig Process

D. Le, A. Bougrine, O. Duclos, V. Pasquet, H. Delalu
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Abstract

A new strategy for the development of monomethylhydrazine (MMH) using the Raschig process is discussed in this publication. The determination of optimal conditions for the synthesis of MMH required the development of a kinetic model. In order to validate the results of the calculation, a device for synthesis under pressure (13 bar) by direct injection of the stoichiometric monochloramine, synthesized using microreactor technology, into monomethylamine (MMA) was developed. The experimental data, in accordance with the theoretical results of the kinetic model, make it possible to establish a new process for the synthesis of monomethylhydrazine.
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Raschig法合成一甲基肼的新工艺
本文讨论了利用拉希法生产单甲基肼的新策略。确定合成MMH的最佳条件需要建立动力学模型。为了验证计算结果,研制了一种用微反应器技术合成的化学计量单氯胺在压力(13 bar)下直接注射合成一甲基胺(MMA)的装置。实验数据与动力学模型的理论结果一致,为建立一种合成一甲基肼的新工艺提供了可能。
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