{"title":"Synthesis of γ-keto sulfones via sulfa-Michael reactions in Brønsted acidic deep eutectic solvent","authors":"Ya-Juan Fan , Dan Wang , Liang Wang","doi":"10.1080/10426507.2023.2240933","DOIUrl":null,"url":null,"abstract":"<div><div>A facile sulfonylation of activated alkenes employing sodium arylsulfinates in Brønsted acidic deep eutectic solvent at room temperature has been developed. The choline chloride/<em>p</em>-toluenesulfonic acid deep eutectic solvent acts both the solvent and as the catalyst, affording the desired <em>γ</em>-keto sulfones in good yields. Easily accessible starting materials, good functional group compatibility as well as simple recovery of the solvent make this procedure environmentally benign.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":"198 12","pages":"Pages 981-985"},"PeriodicalIF":1.4000,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S104265072300182X","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
A facile sulfonylation of activated alkenes employing sodium arylsulfinates in Brønsted acidic deep eutectic solvent at room temperature has been developed. The choline chloride/p-toluenesulfonic acid deep eutectic solvent acts both the solvent and as the catalyst, affording the desired γ-keto sulfones in good yields. Easily accessible starting materials, good functional group compatibility as well as simple recovery of the solvent make this procedure environmentally benign.
期刊介绍：
Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
